Chemical Society Reviews,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
This
review
summarizes
recent
advancements
in
the
synthetic
strategies
of
ionic
porous
materials,
and
highlights
synergistic
interplay
task-specific
interactions
with
pore
structure
key
applications,
including
gas
separation
catalysis.
Journal of the American Chemical Society,
Journal Year:
2024,
Volume and Issue:
146(18), P. 12547 - 12555
Published: April 24, 2024
Three-dimensional
(3D)
crystalline
organic
frameworks
with
complex
topologies,
high
surface
area,
and
low
densities
afford
a
variety
of
application
prospects.
However,
the
design
construction
these
have
been
largely
limited
to
systems
containing
polyhedron-shaped
building
blocks
or
those
relying
on
component
interpenetration.
Here,
we
report
synthesis
3D
framework
based
molecular
mortise-and-tenon
jointing.
This
new
material
takes
advantage
tetra(4-pyridylphenyl)ethylene
chlorinated
bis(benzodioxaborole)benzene
as
is
driven
by
dative
B-N
bonds.
A
single-crystal
X-ray
diffraction
analysis
reveals
presence
two-dimensional
(2D)
layers
helical
channels
that
are
formed
presumably
during
boron-nitrogen
coordination
process.
The
protrusion
dichlorobenzene
units
from
upper
lower
surfaces
2D
facilitates
key
connections.
These
connections
enable
interlocking
adjacent
stabilization
an
overall
framework.
resulting
endowed
porosity
attractive
mechanical
properties,
rendering
it
potentially
suitable
for
removal
impurities
acetylene.
Chemical Science,
Journal Year:
2024,
Volume and Issue:
15(12), P. 4529 - 4537
Published: Jan. 1, 2024
Under
the
guidance
of
reticular
chemistry,
two
isostructural
HOFs
were
constructed
from
8-connected
carboxylic
acids
for
white
light
emission
applications.
Chemical Society Reviews,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
This
review
summarizes
recent
advancements
in
the
synthetic
strategies
of
ionic
porous
materials,
and
highlights
synergistic
interplay
task-specific
interactions
with
pore
structure
key
applications,
including
gas
separation
catalysis.