Chemistry - An Asian Journal,
Journal Year:
2023,
Volume and Issue:
18(21)
Published: Sept. 25, 2023
The
increasing
global
warming
concerns
have
propelled
a
surge
in
the
demand
for
sustainable
energy
sources
within
domain
of
synthetic
organic
chemistry.
A
particularly
prominent
area
research
has
been
development
mild
strategies
generating
heterocyclic
compounds.
Heterocyclic
compounds
containing
boron
notably
risen
to
prominence
as
pivotal
reagents
myriad
transformations,
showcasing
their
wide-ranging
applicability.
This
comprehensive
review
is
aimed
at
collecting
literature
pertaining
borylation
reactions
induced
by
light,
specifically
focusing
on
photocatalyst-free
and
transition
metal-free
methodologies.
central
emphasis
delving
into
selective
mechanistic
investigations.
amalgamation
analysis
these
insights
elucidate
substantial
potential
inherent
eco-friendly
approaches
synthesizing
compounds,
thus
propelling
landscape
ACS Catalysis,
Journal Year:
2023,
Volume and Issue:
13(24), P. 15991 - 16011
Published: Nov. 28, 2023
Carbon
dioxide
radical
anion
(CO2•–)
is
a
highly
reactive
nucleophilic
species
that
has
recently
emerged
in
organic
chemistry
as
strong
single
electron
donor
(reductant)
and
reactant
for
the
synthesis
of
carboxylic
acids.
In
general,
CO2•–
can
be
generated
by
either
direct
reduction
CO2
or
HAT
formate
salts.
Achievements
reactions
involving
have
been
witnessed
recent
years.
This
Review
summarizes
advances
highlighting
some
challenges
identifying
potential
areas
improvement,
which
may
offer
inspiration
future
studies.
Journal of the American Chemical Society,
Journal Year:
2024,
Volume and Issue:
146(18), P. 12300 - 12309
Published: April 24, 2024
Metallaphotoredox
cross-coupling
is
a
well-established
strategy
for
generating
clinically
privileged
aliphatic
scaffolds
via
single-electron
reactivity.
Correspondingly,
expanding
metallaphotoredox
to
encompass
new
C(
RSC Advances,
Journal Year:
2023,
Volume and Issue:
13(16), P. 10958 - 10986
Published: Jan. 1, 2023
The
field
of
photoredox
catalysis
has
been
transformed
by
the
use
organic
photocatalysts,
which
give
access
to
re-activities
that
were
previously
only
possible
with
transition-metal
photocatalysts.
Organic Chemistry Frontiers,
Journal Year:
2024,
Volume and Issue:
11(18), P. 5278 - 5305
Published: Jan. 1, 2024
This
review
summarizes
the
latest
methodological
advances
in
photocatalytic
C(sp
3
)–H
functionalization,
with
a
particular
emphasis
on
formation
of
C–P,
C–B,
C–S
bonds,
etc
.,
and
some
prominent
efforts
asymmetric
C–H
functionalization.
Organic Chemistry Frontiers,
Journal Year:
2024,
Volume and Issue:
11(14), P. 4024 - 4040
Published: Jan. 1, 2024
This
review
provides
a
comprehensive
overview
of
metal
catalysis
in
photo-electrochemical
systems,
discussing
reaction
mechanisms
and
offering
prospects
for
this
triadic
catalytic
mode.
