Reviewing
photocatalytic
and
metal-catalyzed
disulfide
synthesis,
2021–2024,
emphasizes
efficiency,
selectivity,
sustainability
for
drug
material
science.
Organic Chemistry Frontiers,
Journal Year:
2024,
Volume and Issue:
11(18), P. 5278 - 5305
Published: Jan. 1, 2024
This
review
summarizes
the
latest
methodological
advances
in
photocatalytic
C(sp
3
)–H
functionalization,
with
a
particular
emphasis
on
formation
of
C–P,
C–B,
C–S
bonds,
etc
.,
and
some
prominent
efforts
asymmetric
C–H
functionalization.
Organic & Biomolecular Chemistry,
Journal Year:
2024,
Volume and Issue:
22(30), P. 6198 - 6204
Published: Jan. 1, 2024
Reported
herein
is
a
visible-light
induced
selenocyclization
of
2-ethynylanilines
under
ambient
conditions,
with
simple
FeBr
3
as
dual-functional
catalyst.
Organic & Biomolecular Chemistry,
Journal Year:
2024,
Volume and Issue:
22(33), P. 6650 - 6664
Published: Jan. 1, 2024
Titanium,
as
an
important
transition
metal,
has
garnered
extensive
attention
in
both
industry
and
academia
due
to
its
excellent
mechanical
properties,
corrosion
resistance,
unique
reactivity
organic
synthesis.
In
the
field
of
photocatalysis,
titanium-based
compounds
such
titanium
dioxide
(TiO
Advanced Synthesis & Catalysis,
Journal Year:
2024,
Volume and Issue:
366(21), P. 4263 - 4273
Published: Aug. 28, 2024
Abstract
Aryl
radicals
are
important
intermediates
in
organic
synthesis.
The
generation
of
these
reactive
species
via
direct
decarboxylation
inexpensive
and
readily
available
aromatic
carboxylic
acids
is
an
attractive
goal.
However,
such
a
process
intrinsically
exhibits
high
energy
barriers
to
overcome,
which
consequence
usually
require
precious
metal
catalysis,
stoichiometric
oxidants
harsh
conditions,
suffering
from
limitations
as
poor
functional
group
tolerance
low
atom
economy.
In
recent
years,
photochemical
reactions
have
provided
new
approaches
address
this
challenge.
Three
major
strategies
been
introduced
emerging
field:
1)
one‐pot
in‐situ
activation
benzoic
generate
benzoyl
hypobromites
or
hypoiodites;
2)
the
use
specialized
photocatalysts
like
biphenyl/1,4‐dicyanobenzene
promote
through
photo‐induced
electron
transfer
charge
processes;
3)
LMCT
(Ligand‐to‐Metal
Charge
Transfer)
strategy
where
copper
iron
salts
coordinate
carboxylate
anion
upon
visible
light
excitation.
On
basis
three
strategies,
review
will
systematically
summarize
development
visible‐light‐induced
decarboxylative
functionalization
acids,
focusing
on
reaction
mechanism
substrate
scope,
discuss
their
prospects
A
novel
ligand-to-metal
charge
transfer
(LMCT)-based
synthetic
methodology
is
presented
for
the
decarboxylative
hydrogenation
of
aromatic
carboxylic
acids.
This
approach
features
mild
reaction
conditions,
economical
copper-mediated
catalysis,
and
exceptional
functional
group
tolerance.
The
study
addresses
significant
challenges
in
acid
transformations
underscores
potential
photochemical
copper
catalysis
contemporary
organic
synthesis..
Tetrahedron Chem,
Journal Year:
2024,
Volume and Issue:
unknown, P. 100116 - 100116
Published: Dec. 1, 2024
The
indazole
core
is
prevalently
found
in
the
structures
of
bioactive
molecules,
demonstrating
promising
potential
medicinal
chemistry
and
drug
discovery,
which
therefore
has
attracted
sustained
attention
from
synthetic
community.
Over
recent
decades,
significant
progress
been
achieved
both
organic
photocatalysis
electrosynthesis,
offering
novel
approaches
for
efficient
sustainable
synthesis
various
functionalized
indazoles.
This
mini-review
highlights
emerging
methodological
advancements
photo-/electro-chemical
two
common
forms
indazole,
namely
1H-
2H-indazoles,
are
classified
by
specific
intramolecular
bond
formation
patterns:
(1)
C-C
formation,
(2)
C-N
(3)
N-N
formation.
reaction
conditions,
representative
scopes,
mechanistic
understandings
these
protocols
emphasized,
to
elucidate
advantages
limitations
current
strategies,
with
an
aim
inspire
future
innovations
that
may
address
challenges
modern
synthesis.Graphical
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