Green Chemistry,
Journal Year:
2024,
Volume and Issue:
26(9), P. 5127 - 5149
Published: Jan. 1, 2024
This
perspective
provides
the
design,
stability
and
unique
properties
regarding
ionic
liquid-stabilized
metal
oxoclusters
their
application
in
catalysis,
also
illustrates
future
development
of
oxoclusters.
Frontiers in Immunology,
Journal Year:
2024,
Volume and Issue:
15
Published: Aug. 9, 2024
The
field
of
oncology
has
transformed
in
recent
years,
with
treatments
shifting
from
traditional
surgical
resection
and
radiation
therapy
to
more
diverse
customized
approaches,
one
which
is
immunotherapy.
ICD
(immunogenic
cell
death)
belongs
a
class
regulatory
death
modalities
that
reactivate
the
immune
response
by
facilitating
interaction
between
apoptotic
cells
releasing
specific
signaling
molecules,
DAMPs
(damage-associated
molecular
patterns).
inducers
can
elevate
expression
proteins
optimize
TME
(tumor
microenvironment).
use
nanotechnology
shown
its
unique
potential.
Nanomaterials,
due
their
tunability,
targeting,
biocompatibility,
have
become
powerful
tools
for
drug
delivery,
immunomodulators,
etc.,
significant
efficacy
clinical
trials.
In
particular,
these
nanomaterials
effectively
activate
ICD,
trigger
potent
anti-tumor
response,
maintain
long-term
tumor
suppression.
Different
types
nanomaterials,
such
as
biological
membrane-modified
nanoparticles,
self-assembled
nanostructures,
metallic
mesoporous
materials,
hydrogels,
play
respective
roles
induction
structures
mechanisms
action.
Therefore,
this
review
will
explore
latest
advances
application
common
discuss
how
they
provide
new
strategies
cancer
therapy.
By
gaining
deeper
understanding
mechanism
action
researchers
develop
precise
effective
therapeutic
approaches
improve
prognosis
quality
life
patients.
Moreover,
hold
promise
overcome
resistance
conventional
therapies,
minimize
side
effects,
lead
personalized
treatment
regimens,
ultimately
benefiting
treatment.
ACS Applied Materials & Interfaces,
Journal Year:
2024,
Volume and Issue:
16(31), P. 41659 - 41668
Published: July 24, 2024
Recently,
metal–oxo
clusters
(MOCs)
have
attracted
significant
interest
in
fabricating
nanoscale
patterns
semiconductors
via
lithography.
However,
many
MOCs
are
highly
crystalline,
making
it
difficult
for
them
to
form
films
and
hindering
subsequent
nanopatterning
processes.
In
this
study,
we
developed
a
novel
simple
method
enhance
the
film-forming
ability
of
aromatic
tetranuclear
Sn–oxo
by
adding
additives.
Theoretical
calculations
Fourier-transform
infrared
(FTIR)
analysis
revealed
formation
intermolecular
hydrogen
bonds
between
additives,
which
induced
crystal–gel
phase
transition
at
−20
°C,
thereby
inhibiting
easy
crystallization
clusters.
High-quality
uniform
thin
with
surface
roughness
below
0.3
nm
were
prepared
spin
coating.
The
obtained
exhibited
good
lithographic
performance
under
deep
ultraviolet
(DUV),
electron
beam,
extreme-ultraviolet
irradiation
without
photo
acid
generator/photoinitiator,
13-
21
nm-wide
line
on
electron-beam
lithographies.
This
study
will
pave
way
further
investigation
advanced
lithography
other
thin-film
applications.
Advanced Healthcare Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 9, 2024
Abstract
Metal‐organic
frameworks
(MOFs)
have
the
potential
to
revolutionize
biotechnological
and
medical
landscapes
due
their
easily
tunable
crystalline
porous
structure.
Herein,
study
presents
MOFs'
impact
on
proteomics,
unveiling
diverse
roles
MOFs
can
play
boost
it.
Although
are
excellent
catalysts
in
other
scientific
disciplines,
role
as
proteomics
applications
remains
largely
underexplored,
despite
protein
cleavage
being
of
crucial
importance
protocols.
Additionally,
discusses
evolving
MOF
materials
that
tailored
for
showcasing
structural
diversity
functional
advantages
compared
types
used
similar
applications.
be
developed
seamlessly
integrate
into
workflows
features,
contributing
separation,
peptide
enrichment,
ionization
mass
spectrometry.
This
review
is
meant
a
guide
help
bridge
gap
between
material
scientists,
engineers,
chemists
side
researchers
biology
or
bioinformatics
working
proteomics.
Inorganic Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 29, 2025
Two
novel
3D
inorganic-organic
hybrids
based
on
[V6O18]6-/[V3O9]3-
clusters,
[Cu18(bbpy)18(V6O18)6]·3H2O
(1)
and
[Cu4Ag4(pty)4(V3O9)4]·H2O
(2)
(bbpy
=
3,5-bis(1-benzimidazole)
pyridine,
pty
4'-(4″-pyridyl)-2,2':6',2″-terpyridine),
were
isolated
in
the
same
POV/Cu/N-heterocycle
ligand
reaction
systems.
Hybrids
1
2
possess
three-dimensional
bimetallic
frameworks
derived
from
clusters
Cu-organic
complexes.
In
1,
bbpy
ligands
are
grafted
by
Cu2+
to
a
grid
ribbon
2D
sheet,
which
connected
with
benzene-like
[V6O18]6-
yield
framework.
2,
helical
{O-V-O-V-}n
chains
bridged
Cu(II)
ions
into
layer
including
eight-membered
rings
{V6Cu2}
six-membered
{V4Cu2},
adjoining
sheets
joined
Ag-N
coordination
bonds
form
framework
structure.
Moreover,
hybrid
has
superior
electrocatalytic
properties
for
nitrite
reduction
oxidation
of
ascorbic
acid
efficiencies
397.2
96%,
respectively.
Hybrid
displays
coordinated
performance
toward
through
V
Cu
centers.
Meanwhile,
corresponding
theoretical
studies
conducted
evaluate
active
sites
charge
distribution.
