Optimization of novel sustainable Dictyota mertensii alginate films with beeswax using a simplex centroid mixture design DOI
Luiz Paulo de Oliveira Queiroz, Édna Maria Mendes Aroucha, Ricardo Henrique de Lima Leite

et al.

Food Hydrocolloids, Journal Year: 2024, Volume and Issue: 160, P. 110782 - 110782

Published: Oct. 24, 2024

Language: Английский

Robust and durable biodegradable polymer-based triboelectric nanogenerators enabled by trace amounts of melanin-like nanoparticles DOI

Chenyang Pei,

Hengjie Zhang, Yiwen Li

et al.

Nano Energy, Journal Year: 2025, Volume and Issue: 135, P. 110643 - 110643

Published: Jan. 5, 2025

Language: Английский

Citations

11

Three-in-one novel flame retardant through grafting organophosphorus onto Fe-MOF functionalized Mg(OH)2 for improving fire safety and mechanical properties of PBS composites DOI
Li Cui, Long Yu,

Yuanmeng Lou

et al.

Sustainable materials and technologies, Journal Year: 2024, Volume and Issue: 40, P. e00906 - e00906

Published: March 19, 2024

Language: Английский

Citations

10

Biodegradable PLA films incorporating GOZnO hybrid and Mentha Longifolia oil: Fabrication and characterization DOI Open Access

F. Dehghan,

Parsa Dadashi, Amir Babaei

et al.

Polymer Engineering and Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 23, 2025

Abstract The study investigates the effects of graphene oxide/zinc oxide (GO‐ZnO) nanohybrids, combined with Mentha longifolia essential oil, on mechanical, UV resistance, antibacterial, and rheological properties polylactic acid (PLA). GO‐ZnO nanohybrids were prepared at ZnO‐to‐GO ratios 1:1 2:1 incorporated into PLA various concentrations. addition significantly enhanced tensile strength modulus composites due to strong interactions between functionalized nanohybrids. Hydrolytic degradation tests revealed accelerated GO‐ZnO, attributed catalytic ZnO. Rheological analysis showed reduced elasticity higher nanohybrid content, thermal degradation. absorption demonstrated improved protection oil. Antibacterial indicated inhibition percentages against E. coli Listeria , highlighting a synergistic antibacterial effect hybrid system. These findings suggest PLA/GO‐ZnO/oil are promising candidates for packaging applications. Highlights hydrolytic by M. oil catalyze during scission. PBS mechanical via interaction provide in PLA. Thermal analyzed through rheology.

Language: Английский

Citations

1

Synthesis of highly effective polyester/polyacrylate compatibilizers using switchable polymerization DOI Creative Commons

Xiao‐An Fu,

Tian‐Jun Yue, Xiaohui Guo

et al.

Nature Communications, Journal Year: 2025, Volume and Issue: 16(1)

Published: March 4, 2025

Multiblock copolymers (MBCPs) comprising polyester and polyacrylate segments offer an efficient strategy for enhancing the performance of polyolefin blends but synthesis structural modification these MBCPs remains challenging. Here, we propose a method synthesizing via switchable polymerization epoxides, cyclic anhydrides, acrylates using dinuclear Co-complex, wherein anhydride acts as switcher. Detailed studies on copolymerization process reveal that successful is achieved by intramolecular bimetallic synergistic catalysis, producing with controlled molecular weights narrow dispersities. Owing to high compatibility monomers, this allows diverse structures block numbers. Moreover, resulting effectively enhance blends, improving toughness polyesters. Studies microphase separation show can compatibilize immiscible highlighting their potential compatibilizers.

Language: Английский

Citations

1

Exploring Environmental Behaviors and Health Impacts of Biodegradable Microplastics DOI
Yuhao Yan, Jun Cheng, Jie Gao

et al.

Environmental Science & Technology, Journal Year: 2025, Volume and Issue: unknown

Published: March 21, 2025

Biodegradable plastics (BPs) are promoted as eco-friendly alternatives to conventional plastics. However, compared microplastics (MPs), they degrade rapidly into biodegradable (BMPs), which may lead a more significant accumulation of BMPs in the environment. This review systematically compares and MPs, summarizes current knowledge on their environmental behaviors impacts ecosystems human health, offers recommendations for future research. detected water, sediments, indoor dust, food, marine organisms, samples. Compared prone transformations, such photodegradation biodegradation, results shorter migration distance across different matrices. Like can adsorb pollutants transport them enhancing toxicity health risks through Trojan horse effect. Studies indicate that negatively impact terrestrial aquatic than MPs by disrupting nutrient cycling inhibiting plant animal growth. In vivo vitro research also shows BMP degradation products increase bioavailability, exacerbating neurotoxicity overall toxicity. findings BMPs' effects remain inconsistent. Further evaluation trade-offs between biodegradability is needed address these uncertainties.

Language: Английский

Citations

1

Compatibilization of PLA/PBAT blends with epoxidized canola oil for 3D printing applications DOI Creative Commons
Mohamed Wahbi, Quintin Litke, David B. Levin

et al.

Materials Advances, Journal Year: 2024, Volume and Issue: 5(12), P. 5194 - 5203

Published: Jan. 1, 2024

This article outlines an environmentally friendly strategy for producing toughened and compatibilized PLA/PBAT blends, using epoxidized canola oil. Additionally, it explores the potential of these blends use in 3D printing.

Language: Английский

Citations

5

Synergistic enhancement of high-barrier polylactic acid packaging materials by various morphological carbonized cellulose nanocrystals DOI
Bin Wu, Somia Yassin Hussain Abdalkarim, Zhijiang Li

et al.

Carbohydrate Polymers, Journal Year: 2024, Volume and Issue: 351, P. 123118 - 123118

Published: Dec. 7, 2024

Language: Английский

Citations

4

The Journey of Plastics: Historical Development, Environmental Challenges, and the Emergence of Bioplastics for Single-Use Products DOI Creative Commons
Jade Stanley, David Culliton, A. Jonay Jovani‐Sancho

et al.

Eng—Advances in Engineering, Journal Year: 2025, Volume and Issue: 6(1), P. 17 - 17

Published: Jan. 15, 2025

This paper explores the historical development of conventional plastics, tracing their evolution from early forms to pervasive use in modern society. Its observations include rise mass plastic production during World War II and post-war development, showcasing plastics’ economic societal impact. The environmental repercussions pollution have led increased global awareness calls for sustainable alternatives. emergence bioplastics is investigated, including classification, properties, applications, challenges scaling. emphasises urgency adopting a future discusses efforts towards homogenisation standardisation across markets.

Language: Английский

Citations

0

Surface Modification of Polyesters Using Biosourced Soil-Release Polymers DOI Creative Commons
Matthieu Starck, Emanuella F. Fiandra,

J. H. Binks

et al.

JACS Au, Journal Year: 2025, Volume and Issue: 5(2), P. 666 - 674

Published: Feb. 5, 2025

Soil-release polymers (SRPs) are important components of fabric care formulations, performing roles in the cleaning synthetic fabrics. SRPs modify surface textiles and render materials resistant to staining, while offering environmental benefits by enabling effective using shorter, cooler wash cycles. Most used formulations contain petroleum-sourced terephthalic acid, limiting presented use these key additives. Here, we have prepared a selection pyridine dicarboxylate monomers that can be accessed from biomass assessed their ability polyester surfaces. Interestingly, wide range deposition behavior was observed, with soil-release performance significantly impacted component use. The containing 2,5-pyridine units exceeded or comparable current industry-standard SRPs, constructed 2,4- 2,6-pyridine displayed poor performance. Through studies including dynamic light scattering, contact angle analysis, scanning electron microscopy, molecular modeling explored solution interfacial propose observed changes arise combination differences self-assembly variation affinities for Our work highlights potential biosourced starting replacement petroleum-derived within formulated consumer products presents rationale design SRPs.

Language: Английский

Citations

0

Modified Polysaccharides in Laundry Applications as Soil Release and Anti‐Redeposition Additives DOI Creative Commons

Marcellino D'Avino,

Cristina Coelho,

Gang Si

et al.

Journal of Applied Polymer Science, Journal Year: 2025, Volume and Issue: unknown

Published: March 14, 2025

ABSTRACT Polymers play an important role within modern laundry formulations, enhancing their cleaning performance by aiding in the release of soil from textiles and helping to prevent resettling upon during washing. Most these polymers are derived non‐renewable petrochemical sources; however, a combination factors, including consumer preferences commitments manufacturers reduce carbon footprints products while continually improving performance, is driving search for alternatives. In this context, polysaccharides renewable resources (mainly plants, fungi, algae, lichen) offer promising potential as platforms development new agents. Here, we provide extensive overview recent advances polysaccharide‐based additives focusing on synthesis, composition, anti‐redeposition properties. We also present brief technical methods commonly used evaluate polymer additives. hope review will be useful aid those who wish make contributions future with more feedstocks fabric care industry.

Language: Английский

Citations

0