Visible-light induced direct C(sp3)–H functionalization: recent advances and future prospects
Organic Chemistry Frontiers,
Journal Year:
2024,
Volume and Issue:
11(18), P. 5278 - 5305
Published: Jan. 1, 2024
This
review
summarizes
the
latest
methodological
advances
in
photocatalytic
C(sp
3
)–H
functionalization,
with
a
particular
emphasis
on
formation
of
C–P,
C–B,
C–S
bonds,
etc
.,
and
some
prominent
efforts
asymmetric
C–H
functionalization.
Language: Английский
Titanium in photocatalytic organic transformations: current applications and future developments
Organic & Biomolecular Chemistry,
Journal Year:
2024,
Volume and Issue:
22(33), P. 6650 - 6664
Published: Jan. 1, 2024
Titanium,
as
an
important
transition
metal,
has
garnered
extensive
attention
in
both
industry
and
academia
due
to
its
excellent
mechanical
properties,
corrosion
resistance,
unique
reactivity
organic
synthesis.
In
the
field
of
photocatalysis,
titanium-based
compounds
such
titanium
dioxide
(TiO
Language: Английский
Recent Advances in Deoxygenative Thioether Synthesis Using Oxygenated Sulfur Surrogates
Synthesis,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 9, 2025
Abstract
Thioethers
(sulfides)
play
a
crucial
role
in
therapeutics,
diagnostics,
and
functional
materials.
Traditionally,
their
synthesis
involved
the
use
of
thiols
or
derivatives,
which
are
associated
with
unpleasant
odors
potential
health
risks.
Recently,
significant
research
has
focused
on
employing
oxygenated
sulfur
compounds,
such
as
sulfinates,
sulfonyl
oxyacids,
sulfoxides,
thiol
surrogates
for
thioether
synthesis.
This
review
highlights
recent
advancements
deoxygenative
synthesis,
categorizing
them
by
reaction
types,
including
cross-coupling
reactions,
C–H
functionalization,
hydro/halo/oxy-thiolation
unsaturated
hydrocarbons.
We
also
discuss
representative
mechanisms
to
provide
comprehensive
understanding
these
innovative
approaches.
1
Introduction
2
Cross-Coupling
Reactions
3
Functionalization
4
Hydro/Halo/Oxy-thiolation
Unsaturated
Hydrocarbons
5
Conclusion
Language: Английский
Radical 1,3-Hydrosulfonylation of Vinyldiazo Compounds with Sulfinyl Sulfones
Tian Jing,
No information about this author
Yuan‐Li Ding,
No information about this author
Wanting Fu
No information about this author
et al.
Organic Letters,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 4, 2025
Sulfinyl
sulfones,
as
high-valence
sulfurization
reagents,
are
widely
used
to
assemble
sulfur
sources
on
carbon
skeletons,
such
one-,
two-,
and
four-carbon
synthons,
access
organosulfur
compounds.
However,
their
reaction
with
three-carbon
synthons
has
remained
a
mystery
until
now.
We
report
here
radical
1,3-hydrosulfonylation
of
vinyldiazo
compounds
sulfinyl
sulfones.
This
not
only
represents
the
first
example
sulfones
but
also
opens
up
application
in
monofunctionalization.
Language: Английский
Decatungstate-photocatalyzed tandem acylation/cyclization/self-hydrogenation of isocyanides with aldehydes to hydroxyalkylated N-heteroarenes via multiple hydrogen atom transfer
Hong‐Tao Ji,
No information about this author
Qiong-Hui Peng,
No information about this author
Jiasheng Wang
No information about this author
et al.
Green Chemistry,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
A
100%
atom
economical
construction
of
hydroxyalkylated
N-heteroarenes
through
decatungstate-catalyzed
tandem
cyclization/self-hydrogenation
isocyanides
and
aldehydes
under
exogenous
hydrogen
reagent-
byproduct-free
conditions
was
developed.
Language: Английский