Water Research,
Journal Year:
2019,
Volume and Issue:
159, P. 434 - 443
Published: May 15, 2019
A
large
portion
of
the
toxic
effects
observed
in
surface
waters
cannot
be
attributed
to
compounds
regularly
measured
by
water
authorities.
Hence,
there
is
an
urgent
need
for
effect-based
monitoring
strategy
that
employs
bioassays
identify
environmental
risks.
The
aim
present
study
was
perform
nationwide
quality
assessment
ecotoxicological
risks
a
wide
variety
waters.
At
45
locations
silicone
rubbers
and
polar
organic
chemical
integrative
samplers
were
exposed
6
weeks.
Alongside
passive
in-situ
daphnid
test
performed.
Subsequent
field
exposure,
accumulated
extracted
from
after
which
battery
vivo
vitro
extracts.
bioassay
selected
such
it
could
posed
range
pollutants
their
transformation
products,
while
simultaneously
allowing
targeted
identification
groups
cause
specific
effects.
Bioassay
responses
compared
trigger
values
potential
at
investigated
locations.
Responses
all
bioassays,
exceeded
9
out
21
applied
assays,
ranking
based
on
No
relationship
between
land
use
observed.
Based
results,
considerations
regarding
future
improvements
are
given.
It
concluded
allowed
prioritization
sites
risks,
identified
presence
hazardous
regardless
being
listed
as
priority
substances,
meanwhile
prevent
costly
analysis
with
low
Environment International,
Journal Year:
2020,
Volume and Issue:
136, P. 105454 - 105454
Published: Feb. 4, 2020
Interest
in
the
risks
posed
by
trace
concentrations
of
pharmaceuticals
and
personal
care
products
(PPCPs)
surface
waters
is
increasing,
particularly
with
regard
to
potential
effects
long-term,
low-dose
exposures
aquatic
organisms.
In
most
cases,
actual
studies
on
PPCPs
were
risk
assessments
at
screening-level,
accurate
estimates
scarce.
this
study,
exposure
ecotoxicity
data
50
collected
based
our
previous
studies,
a
multiple-level
environmental
assessment
was
performed.
The
selected
are
likely
be
frequently
detected
China,
ranging
from
ng
L-1
low-g
L-1,
quotients
median
ranged
2046
for
nonylphenol
0
phantolide.
A
semi-probabilistic
approach
screened
33
that
organisms,
among
which
15
chemicals
(nonylphenol,
sulfamethoxazole,
di
(2-ethylhexyl)
phthalate,
17β-ethynyl
estradiol,
caffeine,
tetracycline,
17β-estradiol,
estrone,
dibutyl
ibuprofen,
carbamazepine,
tonalide,
galaxolide,
triclosan,
bisphenol
A)
categorized
as
priority
compounds
according
an
optimized
assessment,
then
refined
probabilistic
indicated
12
them
low
high
ecosystem,
maximum
1.54%
17.38%.
Based
these
results,
we
propose
appropriate
screening
contaminants
national
scale,
when
more
estimation
required,
probability
useful.
methodology
process
might
provide
reference
other
research
chemical
evaluation
management
rivers,
lakes,
sea
waters.
Environment International,
Journal Year:
2019,
Volume and Issue:
134, P. 105267 - 105267
Published: Nov. 6, 2019
The
number
of
anthropogenic
chemicals,
manufactured,
by-products,
metabolites
and
abiotically
formed
transformation
products,
counts
to
hundreds
thousands,
at
present.
Thus,
humans
wildlife
are
exposed
complex
mixtures,
never
one
chemical
a
time
rarely
with
only
dominating
effect.
Hence
there
is
an
urgent
need
develop
strategies
on
how
exposure
multiple
hazardous
chemicals
the
combination
their
effects
can
be
assessed.
A
workshop,
“Advancing
Assessment
Chemical
Mixtures
Risks
for
Human
Health
Environment”
was
organized
in
May
2018
together
Joint
Research
Center
Ispra,
EU-funded
research
projects
Commission
Services
relevant
EU
agencies.
This
forum
researchers
policy-makers
created
discuss
identify
gaps
risk
assessment
governance
mixtures
as
well
state
art
science
future
needs.
Based
presentations
discussions
this
workshop
we
want
bring
forward
following
Key
Messages:
We
turning
point:
exposures
combined
require
better
management
protect
public
health
environment
from
mixtures.
Regulatory
initiatives
should
launched
investigate
opportunities
all
regulatory
frameworks
include
prospective
mixture
consider
(real-life)
wildlife,
across
sectors.
Precautionary
approaches
intermediate
measures
(e.g.
Mixture
Factor)
already
applied,
although,
definitive
assessments
cannot
routinely
conducted
due
significant
knowledge
data
gaps.
European
strategy
needs
set,
through
stakeholder
engagement,
would
aimed
scientific
advancement
mechanistic
understanding
modelling
techniques,
address
policy
Without
such
clear
strategy,
specific
objectives
common
priorities,
research,
policies
will
likely
remain
scattered
insufficient.
Journal of Materials Research and Technology,
Journal Year:
2021,
Volume and Issue:
14, P. 2195 - 2218
Published: Aug. 2, 2021
The
article
aims
to
review
the
research
findings
on
adsorption
of
dyes
from
aqueous
media.
It
was
observed
that
activated
carbon
and
Polymer
based
nanomaterial
are
best
class
adsorbents
for
removal
nano
composite
α-Fe2O3/graphene
oxide
(α-Fe2O3/GO)
PAN–polyamidoamine
nanoparticles
dye
media,
with
a
capacity
(qmax)
1998.14
2000
mg/g,
respectively.
A
wide
range
values
thermodynamic
parameters
(both
negative
positive)
were
reported
across
different
studies.
This
suggested
nature
adsorbent
important
factor
in
determining
thermodynamics
adsorption.
Dye
uptake
best-fit
both
Langmuir
Freundlich
isotherm
models
as
well
pseudo-second
order
kinetic
model.
Theoretical
modelling
has
received
lesser
attention;
therefore,
further
investigations
needed
understand
adsorbent–adsorbate
interactions
at
molecular
level.
Environmental Sciences Europe,
Journal Year:
2019,
Volume and Issue:
31(1)
Published: July 15, 2019
Non-target
screening
(NTS)
including
suspect
with
high
resolution
mass
spectrometry
has
already
shown
its
feasibility
in
detecting
and
identifying
emerging
contaminants,
which
subsequently
triggered
exposure
mitigating
measures.
NTS
a
large
potential
for
tasks
such
as
effective
evaluation
of
regulations
safe
marketing
substances
products,
prioritization
monitoring
programmes
assessment
environmental
quality.
To
achieve
this,
further
development
methodology
is
required,
including:
(i)
harmonized
protocols
quality
requirements,
(ii)
infrastructures
efficient
data
management,
sharing
(iii)
sufficient
resources
appropriately
trained
personnel
the
research
regulatory
communities
Europe.
Recommendations
achieving
these
three
requirements
are
outlined
following
discussion
paper.
In
particular,
order
to
facilitate
compound
identification
it
recommended
that
relevant
information
interpretation
spectra,
well
about
compounds
usage
production
tonnages,
should
be
made
accessible
scientific
community
(via
open-access
databases).
For
many
purposes,
implemented
combination
effect-based
methods
focus
on
toxic
chemicals.
The Science of The Total Environment,
Journal Year:
2021,
Volume and Issue:
795, P. 148776 - 148776
Published: July 1, 2021
Monitoring
of
chemicals
in
the
aquatic
environment
by
chemical
analysis
alone
cannot
completely
assess
and
predict
effects
on
species
ecosystems.
This
is
primarily
because
increasing
number
(unknown)
stressors
mixture
present
environment.
In
addition,
ability
ecological
indices
to
identify
underlying
causing
negative
limited.
Therefore,
additional
complementary
methods
are
needed
that
can
address
biological
a
direct
manner
provide
link
exposure,
i.e.
(eco)toxicological
tests.
(Eco)toxicological
tests
defined
as
test
systems
expose
components
(cells,
individuals,
populations,
communities)
(environmental
mixtures
of)
register
effects.
These
measure
responses
at
sub-organismal
(biomarkers
vitro
bioassays),
whole-organismal,
population,
or
community
level.
We
performed
literature
search
obtain
state-of-the-art
overview
ecotoxicological
available
for
assessing
impacts
biota
reveal
datagaps.
total,
we
included
509
biomarkers,
207
bioassays,
422
measuring
whole-organismal
level,
78
population-
community-
ecosystem-level.
Tests
level
biomarkers
were
most
abundant
invertebrates
fish,
whilst
bioassays
mostly
based
mammalian
cell
lines.
ecosystem-level
almost
missing
organisms
other
than
microorganisms
algae.
an
various
extrapolation
challenges
faced
using
data
from
these
suggest
some
forward
looking
perspectives.
Although
extrapolating
measured
relevant
protection
goals
remains
challenging,
combination
experiments
models
key
more
comprehensive
assessment
Environment International,
Journal Year:
2021,
Volume and Issue:
152, P. 106479 - 106479
Published: March 7, 2021
Aquatic
ecosystems
are
at
risk
of
being
impaired
by
various
organic
chemicals,
however
comprehensive
large-scale
evaluations
waterbodies'
status
and
trends
rare.
Here,
surface
water
monitoring
data,
gathered
as
part
the
EU
Water
Framework
Directive
comprising
occurrence
352
contaminants
(>8.3
mil.
measurements;
2001–2015;
8213
sites)
in
31
European
countries,
was
used
to
evaluate
past
current
environmental
risks
for
three
aquatic
species
groups:
fish,
invertebrates,
plants.
Monitoring
quality
indices
were
defined
per
country
found
improve
over
time.
Relationships
became
apparent
between
countries'
index
their
success
detecting
contaminants.
Across
EU,
more
frequently
recent
years.
Overall,
35.7%
(n
=
17,484)
sites
exceeded
least
one
acute
regulatory
threshold
level
(RTL)
each
year,
average
significantly
increased
time
fish
(τ
0.498,
p
0.01)
invertebrates
0.429,
0.03).
This
indicates
an
chemical
pressure
Europe's
waterbodies
overall
exceedances.
Pesticides
identified
main
drivers
(>85%
RTL
exceedances)
with
most
acutely
Europe.
Agricultural
land-use
clearly
primary
spatial
driver
observed
throughout
waters.
Issues
data
heterogeneity
highlighted
also
followed
subsequent
improvement
recommendations,
strengthening
future
assessments.
ecosystem
integrity
remains
across
Europe,
signaling
demand
continued
improvements.
Nanomaterials,
Journal Year:
2020,
Volume and Issue:
10(4), P. 681 - 681
Published: April 4, 2020
Recently,
green-prepared
oxidized
graphenes
have
attracted
huge
interest
in
water
purification
and
wastewater
treatment.
Herein,
reduced
graphene
oxide
(rGO)
was
prepared
by
a
scalable
eco-friendly
method,
its
potential
use
for
the
removal
of
methylene
blue
(MB)
from
systems,
explored.
The
present
work
includes
green
protocol
to
produce
rGO
respective
spectroscopical
morphological
characterizations,
as
well
several
kinetics,
isotherms,
thermodynamic
analyses
successfully
demonstrate
adsorption
MB.
pseudo-second-order
model
appropriated
describe
kinetics
MB
onto
rGO,
suggesting
an
equilibrium
time
30
min.
Otherwise,
Langmuir
more
suitable
indicating
maximum
capacity
121.95
mg
g−1
at
298
K.
In
addition,
demonstrated
that
can
be
treated
mixed
physisorption–chemisorption
process
described
H-bonding,
electrostatic,
π
−
interactions.
These
results
show
remove
cationic
dyes
systems.