Enantioselective Hydrophosphination of Terminal Alkenyl Aza‐Heteroarenes DOI Creative Commons
Esther G. Sinnema, Tizian‐Frank Ramspoth, Reinder H. Bouma

et al.

Angewandte Chemie, Journal Year: 2023, Volume and Issue: 136(7)

Published: Dec. 22, 2023

Abstract This paper presents a Mn(I)‐catalysed methodology for the enantioselective hydrophosphination of terminal alkenyl aza‐heteroarenes. The catalyst operates through H−P bond activation, enabling successful diverse range alkenyl‐heteroarenes with high enantioselectivity. presented protocol addresses inherently low reactivity and commonly encountered suboptimal enantioselectivities these challenging substrates. As an important application we show that this method facilitates synthesis non‐symmetric tridentate P,N,P‐containing ligand like structure in just two synthetic steps using single catalytic system.

Language: Английский

The chemistry of heterocycles in the 21st century DOI
Valery N. Charushin, Egor V. Verbitskiy, О. Н. Чупахин

et al.

Russian Chemical Reviews, Journal Year: 2024, Volume and Issue: 93(7), P. RCR5125 - RCR5125

Published: July 1, 2024

The chemistry of heterocyclic compounds has traditionally been and remains a bright area chemical science in Russia. This is due to the fact that many heterocycles find widest application. These are key structural fragments most drugs, plant protection agents. Many natural also derivatives heterocycles. At present, more than half hundreds millions known collective review devoted achievements Russian chemists this field over last 15–20 years. presents leading heterocyclists representing both RAS institutes university science. It worth noting wide scope review, terms geography author teams, covering whole our large country, diversity research areas. Practically all major types represented review. special attention focused on practical applications design new drugs biologically active compounds, high-energy molecules, materials for organic electronics photovoltaics, ligands coordination chemistry, other rapidly developing advances would not be possible without development fundamental transformations chemistry.<br> Bibliography — 2237 references.

Language: Английский

Citations

41
Pt(II) complexes bearing P,N-donor ligands as catalysts in chemoselective hydrosilylation, hydrogermylation, and hydroboration of terminal alkenes DOI
Hanna Stachowiak, Marcin Gruszczyński, Maciej Kubicki

et al.

Journal of Catalysis, Journal Year: 2024, Volume and Issue: 433, P. 115494 - 115494

Published: April 10, 2024

Language: Английский

Citations

6
Enantioselective Hydrophosphination of Terminal Alkenyl Aza‐Heteroarenes DOI Creative Commons
Esther G. Sinnema, Tizian‐Frank Ramspoth, Reinder H. Bouma

et al.

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 63(7)

Published: Dec. 22, 2023

Abstract This paper presents a Mn(I)‐catalysed methodology for the enantioselective hydrophosphination of terminal alkenyl aza‐heteroarenes. The catalyst operates through H−P bond activation, enabling successful diverse range alkenyl‐heteroarenes with high enantioselectivity. presented protocol addresses inherently low reactivity and commonly encountered suboptimal enantioselectivities these challenging substrates. As an important application we show that this method facilitates synthesis non‐symmetric tridentate P,N,P‐containing ligand like structure in just two synthetic steps using single catalytic system.

Language: Английский

Citations

9
XRD Study of β-Aminophosphine and its Perfluoro-2,1,3-Benzothiadiazole Based Oxide DOI
Boris Yu. Savkov,

R. V. Duritsyn,

Sergey N. Konchenko

et al.

Journal of Structural Chemistry, Journal Year: 2024, Volume and Issue: 65(9), P. 1679 - 1691

Published: Sept. 1, 2024

Language: Английский

Citations

2
Tris(aminomethyl)phosphines and Their Copper(I) (Pseudo)halide Complexes with Aromatic Diimines—A Critical Retrospection DOI Creative Commons
Radosław Starosta

Pharmaceuticals, Journal Year: 2023, Volume and Issue: 16(5), P. 766 - 766

Published: May 19, 2023

Metal complexes feature a wide range of available geometries, diversified lability, controllable hydrolytic stability, and easily rich redox activity. These characteristics, combined with the specific properties coordinated organic molecules, result in many different mechanisms biological action, making each myriads classes metal coordination compounds unique. This focused review presents systematized results studies group copper(I) (pseudo)halide aromatic diimines tris(aminomethyl)phosphines general formula [CuX(NN)PR

Language: Английский

Citations

5
C–P Bond Cleavage Through Hydrogenation in Ruthenium Complexes Supported by P,N Ligands DOI
Vanessa R. G. Cacho, Luı́s F. Veiros, Clara S. B. Gomes

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 26, 2024

The reactivity of ruthenium hydride complexes supported by 2-((di-tert-butylphosphaneyl)methyl)pyridine, L1 and 2-(di-tert-butylphosphaneyl)pyridine, L2, was explored. reaction {Ru(COD)Cl2}x with in the presence base 10 bar H2 gave expected complex [Ru(L1)2(H)Cl], 1, while same L2 [Ru(L2)(P(H)tBu2)(H)Cl], 2, that results from cleavage a C–P bond. We were able to establish under conditions first species formed is [Ru(L2)2(H)Cl], 3, this decomposes give 2 equilibrium [Ru(L2)2Cl2], 4. proposed mechanism obtained DFT has protonation carbon as highest energy step (38.9 kcal/mol), consistent slow reaction. Preliminary studies reveal very active catalyst hydrogenation benzaldehyde (TONs up 44,000).

Language: Английский

Citations

1
A Novel Photoluminescent Ag/Cu Cluster Exhibits a Chromic Photoluminescence Response towards Volatile Organic Vapors DOI Creative Commons
Wei Yang, Shengnan Hu, Yuwei Wang

et al.

Molecules, Journal Year: 2023, Volume and Issue: 28(3), P. 1257 - 1257

Published: Jan. 27, 2023

A new Ag/Cu bimetallic cluster [Ag10Cu6(bdppthi)2(C≡CPh)12(EtOH)2](ClO4)4 (1, bdppthi = N,N'-bis(diphenylphosphanylmethyl)-tetrahydroimidazole) exhibited strong phosphorescent (PL) emission at 644 nm upon excitation 400 nm. Removal of the coordinated EtOH molecules in 1 resulted derivative 1a, which significant red-shifted 678 The structure and PL was restored on exposure to vapor. Cluster 1a also a vapor-chromic response towards other common organic solvent vapors including acetone, MeOH MeCN. PMMA film developed as reusable visible sensor for

Language: Английский

Citations

3
A Multiple Stimuli–Responsive Ag/P/S Complex Showing Solvochromic and Mechanochromic Photoluminescence DOI Creative Commons

Jia‐Jun Yan,

Yu Wu,

Weijia Zhai

et al.

Molecules, Journal Year: 2023, Volume and Issue: 28(14), P. 5513 - 5513

Published: July 19, 2023

The reaction of CF3COOAg, 3-bdppmapy (N,N-bis(diphenylphosphanylmethyl)-3-aminopyridine) and HTZ (1,2,4-triazole-3-thiol) in CH2Cl2/MeOH resulted a dinuclear Ag/P/S complex [Ag2(TZ)2(3-bdppmapy)2]·xSol (1·xSol). Crystals 1·xSol converted to 1·2MeOH air at room temperature further 1 under vacuum upon heating. solid-state, room-temperature photoluminescent emission (510 nm) shifted 494 nm (1·2MeOH) 486 (1). Grinding solids amorphous 1G characterized by solid-state 468 nm, which 1GR with 513 MeOH treatment. returned 1G, this interconversion was reproducible over five cycles. photoluminescence changed response vapors containing low-molecular weight alcohols but remained unchanged after exposure other volatile organic compounds (VOCs) or water vapor. Test papers impregnated could detect methanol from aqueous solutions concentrations above 50%. Complex is, therefore, an example stimuli-responsive molecular sensor for the detection alcohols.

Language: Английский

Citations

3
Tris(aminomethyl)phosphines and Their copper(I) (Pseudo)halide Complexes With Aromatic Diimines – A Critical Retrospection. DOI Open Access
Radosław Starosta

Published: May 16, 2023

Metal complexes feature a wide range of available geometries, diversified lability, controllable hydrolytic stability, and easily rich redox activity. These characteristics combined with the specific properties coordinated organic molecules result in many different mechanisms biological action, making each myriads classes metal coordination compounds unique. This focused review presents systematized results studies group copper(I) (pseudo)halide aromatic diimines tris(aminomethyl)phosphines general formula [CuX(NN)PR3], where X = I- or NCS-, NN 2,2&rsquo;-bipyridyl, 1,10-phenanthroline, 2,9-dimethyl-1,10-phenanthroline 2,2&rsquo;-biquinoline, PR3 Air-stable tris(aminomethyl)phosphines. The structural electronic phosphine ligands luminescent are discussed. 2,9-dimethyl-1,10-phenanthroline, apart from being air- water-stable, exhibit very high vitro antimicriobial activity against Staphylococcus aureus Candida albicans. Moreover, some also show strong antitumor human ovarian carcinoma cell lines: MDAH 2774 SCOV 3, CT26 (mouse colon carcinoma), A549 (human lung adenocarcinoma) lines. tested moderately able to induce DNA lesions through free radical processes, however trends do not reflect observed differences

Language: Английский

Citations

1
A Powerful P−N Connection: Preparative Approaches, Reactivity, and Applications of P‐Stereogenic Aminophosphines DOI Creative Commons
Tanja Huber, Jonathan O. Bauer

Chemistry - A European Journal, Journal Year: 2023, Volume and Issue: 30(18)

Published: Dec. 7, 2023

For more than five decades, P-stereogenic aminophosphine chalcogenides and boranes have attracted scientific attention are still in the focus of ongoing research. In last years, novel transition metal-based synthesis methods been discovered, addition to long-known use chiral auxiliaries. Enantiomerically pure compounds with N-P

Language: Английский

Citations

1