BioResources,
Journal Year:
2024,
Volume and Issue:
19(2), P. 3543 - 3570
Published: April 17, 2024
Raw
and
citric
acid
chemically
treated
date
palm
stone
agro-waste
biomass
(RDSB
CA-MDSB)
powders
were
used
to
remove
an
important
class
of
emerging
industrial
pollutants,
i.e.,
2,4,6-trichlorophenol
(2,4,6-TCP)
from
aqueous
solutions
towards
sustainable
waste
utilization
develop
cost-effective
technology
for
treating
wastewater.
The
characterization
was
performed
by
using
different
analytical
techniques
such
as
CHN
elemental
analysis,
particle
size,
BET,
FTIR,
SEM-EDX,
TGA
analysis.
FTIR
spectral
analysis
revealed
that
the
main
chemical
groups
(N–C,
O=C,
H-O,
H-C,
O–C)
involved
in
trapping
2,4,6-TCP.
highest
adsorption
achieved
with
a
contact
time
150
120
min,
initial
concentration
50-200
mg/L,
biosorbent
dosage
ranging
0.1
1.0
g/L
RDSB
CA-MDSB,
respectively.
experimental
kinetic
data
process
both
adsorbents
fitted
very
well
pseudo-second-order
model
Langmuir
equilibrium
data.
2,4,6-TCP
maximum
monolayer
capacities
53.7,
123.8
mg/g
present
research
confirms
could
be
effective
low-cost
remediation
environment.
Molecules,
Journal Year:
2023,
Volume and Issue:
28(8), P. 3520 - 3520
Published: April 17, 2023
Rapidly
increasing
industrialisation
has
human
needs,
but
the
consequences
have
added
to
environmental
harm.
The
pollution
caused
by
several
industries,
including
dye
generates
a
large
volume
of
wastewater
containing
dyes
and
hazardous
chemicals
that
drains
industrial
effluents.
growing
demand
for
readily
available
water,
as
well
problem
polluted
organic
waste
in
reservoirs
streams,
is
critical
challenge
proper
sustainable
development.
Remediation
resulted
need
an
appropriate
alternative
clear
up
implications.
Nanotechnology
efficient
effective
path
improve
treatment/remediation.
surface
properties
chemical
activity
nanoparticles
give
them
better
chance
remove
or
degrade
material
from
treatment.
AgNPs
(silver
nanoparticles)
are
nanoparticle
treatment
effluent
been
explored
many
studies.
antimicrobial
against
pathogens
well-recognised
health
agriculture
sectors.
This
review
article
summarises
applications
nanosilver-based
particles
removal/degradation
process,
water
management
strategies,
field
agriculture.
Frontiers in Environmental Engineering,
Journal Year:
2024,
Volume and Issue:
3
Published: Jan. 31, 2024
The
review
aimed
to
identify
differences
and
similarities
in
the
adsorption
process
of
five
azo
dyes
[congo
red
(CR),
reactive
black
5
(RB5),
methyl
orange
(MO),
II
(OII),
(MR)]
on
natural
materials,
biosorbents,
industrial
agricultural
waste,
or
biomass,
which
are
alternatives
costly
activated
carbon
locally
available.
were
characterized
compared
based
their
molecular
structure
weight,
water
solubility,
acid
dissociation
constant,
n-octanol-water
partition
coefficient,
maximum
absorbance.
RB5
CR
diazo
dyes,
whereas
MO,
OII,
MR
mono-azo
dyes.
anionic
is
an
dye,
direct
dye.
CR,
RB5,
MR,
OII
molecules
contain
one
more
sulfonate
functional
group(s),
but
does
not.
We
performed
a
literature
following
parameters:
initial
dye
concentration,
adsorbent
dosage,
pH,
temperature,
isotherm,
kinetic
models,
thermodynamic
parameters,
synergetic
competitive
interactions.
tended
adsorb
best
acidic
medium
at
higher
temperatures.
concentration
dosage
studies
indicated
importance
using
appropriate
amount
for
effective
removal.
follow
Langmuir
isotherm
pseudo-second-order
model.
Most
processes
endothermic
spontaneous,
leading
increase
randomness
solid-liquid
interface.
These
results
indicate
between
Relevant
mechanisms
assumed
be
electrostatic
forces,
hydrogen
bonding,
π–π
interactions,
among
others.
Nevertheless,
focus
lies
development
characterization
not
study
influences
from
matrix
“industrial
wastewater”.
Therefore,
research
needed
develop
units
application
textile
industries.
Chemosphere,
Journal Year:
2023,
Volume and Issue:
338, P. 139477 - 139477
Published: July 11, 2023
This
comprehensive
review
explores
the
potential
and
versatility
of
biogenic
materials
as
sustainable
environmentally
benign
alternatives
to
conventional
adsorbents
for
removal
drugs
dyes.
Biogenic
derived
from
plants,
animals,
microorganisms,
algae
biopolymers
have
bioactive
compounds
that
interact
with
functional
groups
pollutants,
resulting
in
their
binding
sorbent.
These
can
be
modified
mechanically,
thermally
chemically
enhance
adsorption
properties.
hybrid
composites,
which
integrate
characteristics
more
than
one
material,
also
been
fabricated.
Additionally,
microorganisms
are
analyzed
ability
uptake
pollutants.
Various
influential
factors
contribute
process
discussed.
The
challenge,
limitations
future
prospects
research
reviewed
bridging
gap
between
large
scale
application
laboratory
scale.
review,
involves
a
combination
various
adsorbents,
going
beyond
existing
literature
where
typically
only
specific
reported.
covers
isotherms,
kinetics,
desorption
studies
providing
an
improved
framework
effective
use
removing
pharmaceuticals
dyes
wastewater.
RSC Advances,
Journal Year:
2024,
Volume and Issue:
14(43), P. 31777 - 31796
Published: Jan. 1, 2024
Safe
drinking
water
and
a
clean
living
environment
are
essential
for
good
health.
However,
the
extensive
growing
use
of
hazardous
chemicals,
particularly
carcinogenic
dyes
like
methylene
blue,
methyl
orange,
rhodamine
B,
malachite
green,
in
both
domestic
industrial
settings,
has
led
to
scarcity
potable
environmental
challenges.
This
trend
poses
serious
threat
human
society,
sustainable
global
development,
marine
ecosystems.
Consequently,
researchers
exploring
more
advanced
methods
beyond
traditional
wastewater
treatment
address
removal
or
degradation
these
toxic
dyes.
Conventional
approaches
often
inadequate
effectively
removing
from
wastewater.
In
this
study,
we
investigated
bimetallic
metal-organic
frameworks
(BMOFs)
as
solution
limitations.
BMOFs
demonstrated
outstanding
dye
capabilities
due
their
multifunctionality,
stability,
large
surface
area,
adjustable
pore
size,
recyclability.
review
provides
comprehensive
overview
research
on
using
BMOFs,
including
synthesis
methods,
types
dyes,
processes
involved
removal,
such
adsorption.
Finally,
discusses
future
potential
emerging
opportunities
treatment.
Sustainability,
Journal Year:
2023,
Volume and Issue:
15(7), P. 5999 - 5999
Published: March 30, 2023
Potentially
toxic
elements
(PTEs)
are
ubiquitous
chemical
compounds
in
the
environment
due
to
contamination
of
air,
water,
or
soil.
They
primarily
sourced
from
fossil
fuel
combustion,
mining
and
smelting,
electroplating,
dyes
pigments,
agricultural
treatments,
plastic
metallic
industries.
These
contaminants
can
produce
various
adverse
effects
when
they
enter
human
body
also
affect
crops
aquatic
ecosystems.
To
address
these
issues,
researchers
developing
techniques,
including
ion
exchange,
membrane
filtration,
photocatalysis,
electrochemical
methods,
bioadsorption,
combinations
processes,
reduce
levels
contaminants,
especially
wastewater.
Among
bioadsorption
has
gained
much
attention
its
high
efficiency,
low
cost,
abundance
adsorbent
materials.
Agricultural
byproducts
used
as
biosorbents
include
rice
husk
bran,
citrus
peel,
banana
coconut
husk,
sugarcane
bagasse,
soybean
hulls,
walnut
almond
shells,
fiber,
barley
straws,
many
others.
Biosorption
capacity
be
described
using
adsorption
kinetic
models
such
Elovich,
Ritchie’s,
pseudo-second-order
models,
well
different
isotherm
Freundlich,
Langmuir,
Temkin
isotherm,
BET
models.
Both
conventional
processes
influenced
by
parameters
pH,
agitation
speed,
contact
time,
particle
size,
concentration
material,
initial
contaminant,
type
modifying
agent
used.
This
review
paper
aims
examine
low-cost
adsorbents
their
removal
efficiency
for
PTEs
present
wastewater,
potential
decontamination
methods.
Materials,
Journal Year:
2023,
Volume and Issue:
16(11), P. 4082 - 4082
Published: May 30, 2023
In
this
study,
a
new
eco-friendly
kaolinite-cellulose
(Kaol/Cel)
composite
was
prepared
from
waste
red
bean
peels
(Phaseolus
vulgaris)
as
source
of
cellulose
to
serve
promising
and
effective
adsorbent
for
the
removal
crystal
violet
(CV)
dye
aqueous
solutions.
Its
characteristics
were
investigated
through
use
X-ray
diffraction,
Fourier-transform
infrared
spectroscopy,
scanning
electron
microscopy,
energy-dispersive
zero-point
charge
(pHpzc).
The
Box-Behnken
design
used
improve
CV
adsorption
on
by
testing
its
primary
affecting
factors:
loading
Cel
into
matrix
Kaol
(A:
0-50%),
dosage
(B:
0.02-0.05
g),
pH
(C:
4-10),
temperature
(D:
30-60
°C),
duration
(E:
5-60
min).
significant
interactions
with
greatest
elimination
efficiency
(99.86%)
are
follows:
BC
(adsorbent
dose
vs.
pH)
BD
temperature)
at
optimum
parameters
25%,
B:
0.05
g,
C:
10,
D:
45
°C,
E:
17.5
min)
which
CV's
best
capacity
(294.12
mg/g)
recorded.
Freundlich
pseudo-second-order
kinetic
models
isotherm
fitting
our
results.
Furthermore,
study
mechanisms
responsible
eliminating
utilizing
Kaol/Cel-25.
It
detected
multiple
types
associations,
including
electrostatic,
n-π,
dipole-dipole,
hydrogen
bonding
interactions,
Yoshida
bonding.
These
findings
suggest
that
Kaol/Cel
could
be
starting
material
developing
highly
efficient
can
remove
cationic
dyes
environments.