Royal Society of Chemistry eBooks,
Journal Year:
2024,
Volume and Issue:
unknown, P. 106 - 156
Published: Nov. 15, 2024
This
solid-state
NMR
report
summarises
the
subject
and
results
of
selected
articles
original
papers
published
in
2023.
In
addition
to
reviews,
two
major
sections
this
consider
various
methodological
developments
a
broad
range
applications.
The
presented
classification
into
different
subsections
is
intended
ease
overview
results,
as
well
evaluate
directions
which
techniques
applications
are
likely
develop
near
future.
overall
survey
indicates
that
number
electrolyte
battery
materials
studies
by
has
increased
considerably
2023
compared
previous
years.
Polymer Journal,
Journal Year:
2024,
Volume and Issue:
56(4), P. 249 - 268
Published: Jan. 12, 2024
Abstract
Over
8
billion
tons
of
plastic
have
been
produced
to
date,
and
a
100%
reclamation
recycling
strategy
is
not
foreseeable.
This
review
summarizes
how
the
mechanochemistry
polymers
may
contribute
sustainable
polymer
future
by
controlling
degradation
only
de
novo
developed
designer
but
also
plastics
in
existing
waste
streams.
The
historical
development
presented
while
highlighting
current
examples
mechanochemically
induced
degradation.
Additionally,
theoretical
computational
frameworks
are
discussed
that
lead
discovery
better
understanding
new
mechanochemical
reactions
future.
takes
into
account
technical
engineering
perspectives
converging
fields
trituration
with
particular
focus
on
fate
commodity
potential
technologies
monitor
they
occur.
Therefore,
unique
perspective
multiple
communities
presented,
need
for
transdisciplinary
research
tackle
high-leverage
parameters
governing
an
eventually
successful
approach
circular
economy.
Physical Chemistry Chemical Physics,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
We
present
mcRS,
a
high-sensitivity
free-space
optics
Raman
system
for
in
situ
mechanochemical
monitoring.
It
improves
spectral
and
time
resolution,
costs
five
times
less
than
commercial
systems,
uniquely
enables
simultaneous
rheology
Green Chemistry,
Journal Year:
2024,
Volume and Issue:
26(14), P. 8341 - 8347
Published: Jan. 1, 2024
Resonant
Acoustic
Mixing
(RAM)
allows
High
Throughput
Experimentation
(HTE)
using
commercially
available
96-well
plates
as
exemplified
by
the
nickel
catalyzed
C–N
cross
coupling
of
aryl
halides
with
different
amine
and
anilines.
ChemPhysChem,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Aug. 12, 2024
Abstract
Noncovalent
interactions
are
the
basis
for
a
large
number
of
chemical
and
biological
molecular‐recognition
processes,
such
as
those
occurring
in
supramolecular
chemistry,
catalysis,
solid‐state
reactions
mechanochemistry,
protein
folding,
protein‐nucleic
acid
binding,
biomolecular
phase
separation
processes.
In
this
perspective
article,
some
recent
developments
probing
noncovalent
by
proton‐detected
Nuclear
Magnetic
Resonance
(NMR)
spectroscopy
at
Magic‐Angle
Spinning
(MAS)
frequencies
100
kHz
more
reviewed.
The
development
MAS
rotors
with
decreasing
outer
diameters,
combined
superconducting
magnets
operating
high
static
magnetic‐field
strengths
up
to
28.2
T
(1200
MHz
proton
Larmor
frequency)
improves
resolution
sensitivity
NMR,
which
is
fundamental
requirement
shedding
light
on
solids.
examples
reported
article
range
from
binding
ATP‐fueled
motor
proteins
hydrogen‐π
interaction
calixarene‐lanthanide
complex.
ACS Sustainable Chemistry & Engineering,
Journal Year:
2024,
Volume and Issue:
12(43), P. 15875 - 15880
Published: Oct. 15, 2024
A
mechanochemical
copper-catalyzed
oxidative
amination
of
primary
sulfinamides
has
been
developed,
leading
to
NH-sulfonimidamides
in
moderate
good
yields
under
solvent-free
conditions.
Air
serves
as
a
terminal
oxidant
without
the
need
for
external
additives.
The
obtained
products
could
be
readily
converted
into
both
acyclic
and
cyclic
sulfonimidamide
derivatives.
This
approach
demonstrates
considerable
ecological
benefits
compared
solvent-based
methods.
RSC Mechanochemistry,
Journal Year:
2024,
Volume and Issue:
1(3), P. 219 - 227
Published: Jan. 1, 2024
Zinc
bionanohybrids
have
been
synthesised
by
a
mechanochemical
method
that
involves
size
effect
at
the
nano-
and
microscale
levels
of
final
structure,
improving
their
catalytic
properties
compared
to
counterpart
in
water.
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 9, 2024
Abstract
Starting
from
N
‐acyl
sulfonimidamides,
mechanochemically
generated
rhodium
nitrenoids
undergo
intramolecular
N−O
couplings
to
provide
unprecedented
1,3,2,4‐oxathiadiazole
3‐oxides
in
good
excellent
yields.
The
cyclization
proceeds
efficiently
with
a
catalyst
loading
of
only
0.5
mol
%
the
presence
phenyliodine(III)
diacetate
(PIDA)
as
oxidant.
Neither
an
inert
atmosphere
nor
additional
heating
is
required
this
solvent‐free
procedure.
Under
heat
or
blue
light,
newly
formed
five‐membered
heterocycles
function
nitrene
precursors
reacting
sulfoxides
exemplified
by
imidation
dimethyl
sulfoxide.
