Angewandte Chemie,
Journal Year:
2022,
Volume and Issue:
134(37)
Published: July 5, 2022
Abstract
Ionic
liquids
(ILs)
and
deep
eutectic
solvents
(DESs)
debuted
with
a
promise
of
superior
sustainability
footprint
due
to
their
low
vapor
pressure.
However,
toxicity
high
cost
compromise
this
footprint,
impeding
real‐world
applications.
Fortunately,
property
tunability
through
rational
selection
precursors,
including
bioderived
ones,
provides
strategy
ameliorate
toxicity,
lower
cost,
endow
new
functions.
This
Review
discusses
whether
ILs
DESs
are
sustainable
how
they
contribute
chemical
processes.
Angewandte Chemie International Edition,
Journal Year:
2019,
Volume and Issue:
59(3), P. 1018 - 1029
Published: July 11, 2019
Abstract
Mechanochemical
solvent‐free
reactions
by
milling,
grinding
or
other
types
of
mechanical
action
have
emerged
as
a
viable
alternative
to
solution
chemistry.
Mechanochemistry
offers
not
only
possibility
eliminate
the
need
for
bulk
solvent
use,
and
reduce
generation
waste,
but
it
also
unlocks
door
different
reaction
environment
in
which
synthetic
strategies,
molecules
previously
accessible
solution,
can
be
achieved.
This
Minireview
examines
potential
mechanochemistry
chemical
materials
synthesis,
providing
cross‐section
recent
developments
using
ball
milling
formation
based
on
covalent
coordination
bonds.
ChemSusChem,
Journal Year:
2021,
Volume and Issue:
14(10), P. 2145 - 2162
Published: April 9, 2021
In
recent
years,
mechanochemistry
has
been
growing
into
a
widely
accepted
alternative
for
chemical
synthesis.
addition
to
their
efficiency
and
practicality,
mechanochemical
reactions
are
also
recognized
sustainability.
The
association
between
Green
Chemistry
often
originates
from
the
solvent-free
nature
of
most
protocols,
which
can
reduce
waste
production.
However,
satisfies
more
than
one
Principles
Chemistry.
this
Review
we
will
present
series
examples
that
clearly
illustrate
how
significantly
contribute
fulfillment
in
holistic
manner.
Angewandte Chemie,
Journal Year:
2019,
Volume and Issue:
132(3), P. 1030 - 1041
Published: July 11, 2019
Abstract
Mechanochemical
solvent‐free
reactions
by
milling,
grinding
or
other
types
of
mechanical
action
have
emerged
as
a
viable
alternative
to
solution
chemistry.
Mechanochemistry
offers
not
only
possibility
eliminate
the
need
for
bulk
solvent
use,
and
reduce
generation
waste,
but
it
also
unlocks
door
different
reaction
environment
in
which
synthetic
strategies,
molecules
previously
accessible
solution,
can
be
achieved.
This
Minireview
examines
potential
mechanochemistry
chemical
materials
synthesis,
providing
cross‐section
recent
developments
using
ball
milling
formation
based
on
covalent
coordination
bonds.
Chemistry - A European Journal,
Journal Year:
2021,
Volume and Issue:
27(23), P. 6819 - 6847
Published: Jan. 15, 2021
The
mechanochemical
synthesis
of
nanomaterials
for
catalytic
applications
is
a
growing
research
field
due
to
its
simplicity,
scalability,
and
eco-friendliness.
Besides,
it
provides
materials
with
distinct
features,
such
as
nanocrystallinity,
high
defect
concentration,
close
interaction
the
components
in
system,
which
are,
most
cases,
unattainable
by
conventional
routes.
Consequently,
this
has
recently
become
highly
popular,
particularly
preparation
various
applications,
ranging
from
chemical
production
over
energy
conversion
catalysis
environmental
protection.
In
Review,
recent
studies
on
mechanochemistry
are
discussed.
Emphasis
placed
straightforwardness
route-in
contrast
more
synthesis-in
fabricating
materials,
otherwise
often
require
harsh
conditions.
Distinct
material
properties
achieved
related
their
improved
performance.
Advanced Synthesis & Catalysis,
Journal Year:
2019,
Volume and Issue:
362(1), P. 3 - 64
Published: Oct. 15, 2019
Abstract
The
synthetic
strategies
towards
thiosulfonates
(RSO
2
SR
1
)
are
comprehensively
reviewed
from
their
original
discovery
to
recent
advances.
Incorporation
of
the
green
credentials
procedures
allows
one
judge
merits
state
art,
beyond
typical
yield
a
product
and
availability
reactants.
As
reactant
for
organic
transformations,
particularly
interesting
given
possibility
react
with
nucleophiles,
electrophiles
radicals.
This
review
aims
give
researchers,
not
familiar
field,
good
understanding
general
applications
thiosulfonates,
while
skipping
important
related,
but
less
explored,
selenosulfonates
SeR
also
covered.
magnified
image
Chemistry - A European Journal,
Journal Year:
2021,
Volume and Issue:
27(38), P. 9721 - 9726
Published: April 1, 2021
Abstract
Recent
research
endeavors
have
established
that
the
mechanochemical
activation
of
piezoelectric
materials
can
open
new
avenues
in
redox
chemistry.
Impact
forces,
such
as
those
imparted
by
a
ball
mill,
been
shown
to
transform
barium
titanate
(BaTiO
3
)
into
highly
polarized
state,
which
then
donate
an
electron
suitable
oxidant
and
receive
from
reductant,
mimicking
photoredox
catalytic
cycles.
Proof‐of‐concept
studies
elucidated
mechanoredox
chemistry
holds
great
potential
sustainable
efficient
radical‐based
synthesis.
Angewandte Chemie International Edition,
Journal Year:
2022,
Volume and Issue:
61(37)
Published: July 5, 2022
Ionic
liquids
(ILs)
and
deep
eutectic
solvents
(DESs)
debuted
with
a
promise
of
superior
sustainability
footprint
due
to
their
low
vapor
pressure.
However,
toxicity
high
cost
compromise
this
footprint,
impeding
real-world
applications.
Fortunately,
property
tunability
through
rational
selection
precursors,
including
bioderived
ones,
provides
strategy
ameliorate
toxicity,
lower
cost,
endow
new
functions.
This
Review
discusses
whether
ILs
DESs
are
sustainable
how
they
contribute
chemical
processes.
Angewandte Chemie International Edition,
Journal Year:
2020,
Volume and Issue:
59(50), P. 22570 - 22576
Published: Sept. 14, 2020
Abstract
The
application
of
piezoelectricity
for
the
generation
trifluoromethyl
(CF
3
)
radicals
is
reported
together
with
development
a
method
mechanochemical
C−H
trifluoromethylation
aromatic
compounds.
As
compared
to
conventional
solution‐based
approaches,
this
mechanoredox
enables
cleaner
and
more
sustainable
access
wide
range
trifluoromethylated
N‐heterocycles
peptides,
which
are
important
structural
motifs
in
modern
drug
discovery.
This
study
thus
represents
an
milestone
future
applications
systems
medicinal
pharmaceutical
science.
Chemistry - A European Journal,
Journal Year:
2020,
Volume and Issue:
26(57), P. 12903 - 12911
Published: April 21, 2020
Abstract
Direct
mechanocatalysis
describes
catalytic
reactions
under
the
involvement
of
mechanical
energy
with
distinct
feature
milling
equipment
itself
being
catalyst.
This
novel
type
catalysis
features
no
solubility
challenges
catalysts
nor
substrate
and
on
top
offering
most
facile
way
separation.
Angewandte Chemie International Edition,
Journal Year:
2020,
Volume and Issue:
60(12), P. 6660 - 6666
Published: Oct. 8, 2020
The
mechanochemical,
solvent-free,
highly
regioselective,
rhodium-catalyzed
C-H
methylation
of
(hetero)arenes
is
reported.
reaction
shows
excellent
functional-group
compatibility
and
demonstrated
to
work
for
the
late-stage
biologically
active
compounds.
method
requires
no
external
heating
benefits
from
considerably
shorter
times
than
previous
solution-based
protocols.
Additionally,
mechanochemical
approach
shown
enable
efficient
synthesis
organometallic
complexes
that
are
difficult
generate
conventionally.
