Proton Conduction in Zirconium-Based Metal–Organic Frameworks for Advanced Applications DOI Creative Commons

Kai-Xin Zhao,

Guo-Qin Zhang,

Xinru Wu

et al.

ACS Applied Electronic Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 3, 2025

Zirconium-based metal-organic frameworks (Zr-MOFs) have emerged as a promising class of crystalline porous materials, attracting significant interest in the field proton conduction due to their exceptional chemical stability, structural flexibility, and functional tunability. Notably, proton-conducting Zr-MOFs show immense potential for diverse advanced technological applications. In this Spotlight on Applications paper, we provide an overview spotlight recent progress utilization exchange membranes membrane fuel cells (PEMFCs), light-responsive systems pumps, sensors formic acid detection. Furthermore, also discussed challenges, future prospects, opportunities promoting application Zr-MOFs.

Language: Английский

Mn MOF-derivatives synthesized based upon a mechanochemistry method for low-temperature NH3- SCR: From amorphous precursor to amorphous catalyst DOI
Shi-Min Li, Chuanqiang Li, Cui Liu

et al.

Molecular Catalysis, Journal Year: 2024, Volume and Issue: 554, P. 113767 - 113767

Published: Jan. 9, 2024

Language: Английский

Citations

12

Metal–Organic Framework‐Based Nanomaterials for Regulation of the Osteogenic Microenvironment DOI

Wenzhuo Zheng,

Zihan Meng, Zhou Zhu

et al.

Small, Journal Year: 2024, Volume and Issue: 20(29)

Published: Feb. 20, 2024

As the global population ages, bone diseases have become increasingly prevalent in clinical settings. These conditions often involve detrimental factors such as infection, inflammation, and oxidative stress that disrupt homeostasis. Addressing these disorders requires exogenous strategies to regulate osteogenic microenvironment (OME). The regulation of OME can be divided into four processes: induction, modulation, protection, support, each serving a specific purpose. To this end, metal-organic frameworks (MOFs) are an emerging focus nanomedicine, which show tremendous potential due their superior delivery capability. MOFs play numerous roles metal ion donors, drug carriers, nanozymes, photosensitizers, been extensively explored recent studies. This review presents comprehensive introduction by MOF-based nanomaterials. By discussing various functional MOF composites, work aims inspire guide creation sophisticated efficient nanomaterials for disease management.

Language: Английский

Citations

12

Microporous Materials in Polymer Electrolytes: The Merit of Order DOI
Ming Xu, Danyang Li,

Yuhe Feng

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(35)

Published: June 25, 2024

Solid-state batteries (SSBs) have garnered significant attention in the critical field of sustainable energy storage due to their potential benefits safety, density, and cycle life. The large-scale, cost-effective production SSBs necessitates development high-performance solid-state electrolytes. However, manufacturing relies heavily on advancement suitable Composite polymer electrolytes (CPEs), which combine advantages ordered microporous materials (OMMs) electrolytes, meet requirements for high ionic conductivity/transference number, stability with respect electrodes, compatibility established processes, cost-effectiveness, making them particularly well-suited mass SSBs. This review delineates how structural ordering dictates fundamental physicochemical properties OMMs, including ion transport, thermal transfer, mechanical stability. applications prominent OMMs are critically examined, such as metal-organic frameworks, covalent organic zeolites, CPEs, highlighting facilitates fulfillment property requirements. Finally, an outlook is provided, exploring CPEs can be enhanced through dimensional design importance uncovering underlying "feature-function" mechanisms various CPE types underscored.

Language: Английский

Citations

12

Defective ordered macroporous ZIF–8/ZnO heterostructure for enhanced visible–light photo–oxidation performance DOI

Yongjun Fu,

Xiaojie Yao,

Xinfei Ji

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 983, P. 173899 - 173899

Published: Feb. 16, 2024

Language: Английский

Citations

10

Au bipyramids@CuZn MOF core-shell nanozyme enables universal SERS and colorimetric dual-model bioassay DOI
Mengdi Wang, Feng Shi, Jiayin Li

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(47), P. 6019 - 6022

Published: Jan. 1, 2024

In this study, a new type of gold nano-bipyramids@CuZn bimetallic organic framework (AuNBPs@CuZn MOF) nanozyme with high peroxidase (POD)-like activity and surface enhanced Raman scattering (SERS) was constructed special core-shell structure, which can catalyze the oxidation TMB (colourless Raman-inactive) into ox-TMB (blue Raman-active). An AuNBPs@CuZn MOF-enabling universal SERS colorimetric dual-model bioassay thus developed for biomolecules excellent performance, has promising application prospects in biosensing fields.

Language: Английский

Citations

10

Bone targeted nano-drug and nano-delivery DOI Creative Commons
Yilun Wu, Bing Sun, Ying Tang

et al.

Bone Research, Journal Year: 2024, Volume and Issue: 12(1)

Published: Sept. 4, 2024

Language: Английский

Citations

10

Two photochromic two-dimensional Zn(II)-MOFs based on a carboxybenzyl viologen ligand DOI
Jiali Chen, Yuying Fu, Shou-Jie Shen

et al.

Dyes and Pigments, Journal Year: 2024, Volume and Issue: 229, P. 112291 - 112291

Published: June 17, 2024

Language: Английский

Citations

8

Green preparation of metal–organic frameworks in deep eutectic systems with boosted photocatalytic activity DOI Open Access
Wenqian Jiang, Yumei Chen,

Xinru Ding

et al.

Journal of Chemical Technology & Biotechnology, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 29, 2025

Abstract Background Metal–organic frameworks (MOFs) are known for their extensive specific surface area, robust stability, and diverse active sites, which make them highly effective applications in photocatalysis. The deep eutectic system (DESys) offers a green alternative to traditional toxic organic solvents can impart novel, eco‐friendly properties synthesized materials. This study investigates DESys/MIL‐100(Fe), MOF within DESys, its application the photocatalytic decomposition of tetracycline hydrochloride (TC‐HCl). Compared conventional synthesis methods, DESys‐based approach avoids use hydrofluoric acid high‐pressure reaction equipment, making it more environmentally friendly potentially suitable large‐scale industrial production MOFs. Results results showed that DESys/MIL‐100(Fe) demonstrated significantly better performance TC‐HCl degradation than MIL‐100(Fe) by methods. After 2 h visible‐light exposure, efficiency reached 91.20% with while was only 38.74% under identical conditions. improved be attributed enhanced adsorption capabilities, increased number greater absorption visible light, higher carrier density. These factors contribute superior catalytic efficiency. Conclusion findings demonstrate not exhibits outstanding stability pollutants but also highlights potential using DESys high‐performance sustainable pathway MOFs environmental applications. © 2025 Society Chemical Industry (SCI).

Language: Английский

Citations

1

Nanoparticle-Based Drug Delivery Systems for Enhancing Bone Regeneration DOI
Hang Xu, Yutao Cui,

Yuhang Tian

et al.

ACS Biomaterials Science & Engineering, Journal Year: 2024, Volume and Issue: 10(3), P. 1302 - 1322

Published: Feb. 12, 2024

The treatment of bone defects has been a long-standing challenge in clinical practice. Among the various tissue engineering approaches, there substantial progress development drug delivery systems based on functional drugs and appropriate carrier materials owing to technological advances recent years. A large number nanocarriers have developed applied improve complex osteogenic microenvironment, including for promoting activity, inhibiting osteoclast exerting certain antibacterial effects. This Review discusses physicochemical properties, loading mechanisms, advantages disadvantages nanoparticles (NPs) used constructing systems. In addition, we provide an overview microenvironment regulation mechanism nanoparticle (NP) carriers construction strategies Finally, NP are summarized along with their prospects future research trends engineering. thus provides advanced design application NPs defects.

Language: Английский

Citations

8

Synthesis, magnetic and fluorescence detection properties of four metal-organic frameworks based on imidazole carboxylic acid ligands DOI

Jianbo Huang,

Lin Yin,

Tian‐Cai Yue

et al.

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1309, P. 138229 - 138229

Published: April 3, 2024

Language: Английский

Citations

7