Inorganic Chemistry,
Journal Year:
2023,
Volume and Issue:
62(40), P. 16288 - 16293
Published: Sept. 28, 2023
The
effective
discrimination
and
determination
of
the
chiral
antimalarial
drugs
quinine
(QN)
quinidine
(QD)
are
extremely
important
for
human
health.
Herein,
a
2D
achiral
Sm-based
metal–organic
framework
(IMU-MOF1
=
[Sm(tpba)(L)]n,
where
Htpba
4-(2,2′:6″,2′-terpyridin)-4′-ylbenzioc
acid
H2L
2,2′-biquinoline-4,4′-dicarboxylic
acid)
was
successfully
prepared
by
solvothermal
method.
More
importantly,
IMU-MOF1
designed
as
an
ultrasensitive
fluorescent
probe
identification
enantiomer
drugs.
limits
detection
QN
QD
4.24
×
10–11
7.54
10–12
M,
respectively.
Furthermore,
it
demonstrated
that
stronger
hydrogen-bonding
interactions
between
furnish
more
efficient
energy
transfer
to
ligands
in
sensing
process,
resulting
significant
fluorescence
enhancement
IMU-MOF1.
Heliyon,
Journal Year:
2024,
Volume and Issue:
10(3), P. e25521 - e25521
Published: Feb. 1, 2024
Nanomaterials
(NMs)
have
garnered
significant
attention
in
recent
decades
due
to
their
versatile
applications
a
wide
range
of
fields.
Thanks
tiny
size,
enhanced
surface
modifications,
impressive
volume-to-surface
area
ratio,
magnetic
properties,
and
customized
optical
dispersion.
NMs
experienced
an
incredible
upsurge
biomedical
including
diagnostics,
therapeutics,
drug
delivery.
This
minireview
will
focus
on
notable
examples
that
tackle
important
issues,
demonstrating
various
aspects
such
as
design,
synthesis,
morphology,
classification,
use
cutting-edge
applications.
Furthermore,
we
classified
outlined
the
distinctive
characteristics
advanced
nanoscale
particles
hybrid
NMs.
Meanwhile,
emphasize
potential
metal-organic
frameworks
(MOFs),
highly
group
These
MOFs
gained
recognition
promising
candidates
for
bio-applications,
bioimaging,
biosensing,
antiviral
therapy,
anticancer
nanomedicines,
theranostics,
immunotherapy,
photodynamic
photothermal
gene
Although
shown
great
field,
clinical
is
still
limited
by
issues
stability,
cytotoxicity,
biocompatibility,
health
concerns.
review
article
provides
thorough
analysis
offering
valuable
insights
researchers
investigating
explore
new
development,
expansion
opportunities.
Remarkably,
ponder
prospects
nanocomposites
conjunction
with
current
technology.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(18)
Published: Jan. 19, 2024
Abstract
Machine
learning
holds
significant
research
potential
in
the
field
of
nanotechnology,
enabling
nanomaterial
structure
and
property
predictions,
facilitating
materials
design
discovery,
reducing
need
for
time‐consuming
labor‐intensive
experiments
simulations.
In
contrast
to
their
achiral
counterparts,
application
machine
chiral
nanomaterials
is
still
its
infancy,
with
a
limited
number
publications
date.
This
despite
great
advance
development
new
sustainable
high
values
optical
activity,
circularly
polarized
luminescence,
enantioselectivity,
as
well
analysis
structural
chirality
by
electron
microscopy.
this
review,
an
methods
used
studying
provided,
subsequently
offering
guidance
on
adapting
extending
work
nanomaterials.
An
overview
within
framework
synthesis–structure–property–application
relationships
presented
insights
how
leverage
study
these
highly
complex
are
provided.
Some
key
recent
reviewed
discussed
Finally,
review
captures
achievements,
ongoing
challenges,
prospective
outlook
very
important
field.
Advanced Science,
Journal Year:
2024,
Volume and Issue:
11(13)
Published: Jan. 24, 2024
Chiral
CDots
(c-CDots)
not
only
inherit
those
merits
from
but
also
exhibit
chiral
effects
in
optical,
electric,
and
bio-properties.
Therefore,
c-CDots
have
received
significant
interest
a
wide
range
of
research
communities
including
chemistry,
physics,
biology,
device
engineers.
They
already
made
decent
progress
terms
synthesis,
together
with
the
exploration
their
optical
properties
applications.
In
this
review,
chiroptical
chirality
origin
extinction
circular
dichroism
(ECD)
circularly
polarized
luminescence
(CPL)
is
briefly
discussed.
Then,
synthetic
strategies
summarized,
one-pot
post-functionalization
ligands,
assembly
into
architectures
soft
templates.
Afterward,
on
applications
are
elaborated.
Research
domains
such
as
drug
delivery,
bio-
or
chemical
sensing,
regulation
enzyme-like
catalysis,
others
covered.
Finally,
perspective
challenges
associated
strategies,
understanding
chirality,
potential
provided.
This
review
discusses
latest
developments
helps
toward
better
structure-property
relationship
along
respective
Chemical Science,
Journal Year:
2023,
Volume and Issue:
14(21), P. 5593 - 5601
Published: Jan. 1, 2023
Chiral
copper
clusters
displaying
good
luminescence
and
extended
lifetimes
were
synthesised.
Enantiomerically
pure
capped
using
l
-
d
-isomers
of
the
ligand
displayed
mirror
image
circular
dichroism
circularly
polarized
luminescence.
Chemical Communications,
Journal Year:
2023,
Volume and Issue:
59(17), P. 2399 - 2412
Published: Jan. 1, 2023
This
feature
article
focuses
on
introducing
three
kinds
of
non-invasive
imaging
technology,
i.e.
,
fluorescence,
ultrasonic
and
photoacoustic
imaging,
in
which
optical
and/or
acoustic
signals
are
employed
for
diagnosing
various
diseases.
ACS Nano,
Journal Year:
2023,
Volume and Issue:
17(17), P. 16326 - 16347
Published: Aug. 4, 2023
Chiral
inorganic
nanomaterials
due
to
their
unique
asymmetric
nanostructures
have
gradually
demonstrated
intriguing
chirality-dependent
performance
in
photo(electro)catalytic
conversion,
such
as
water
splitting.
However,
understanding
the
correlation
between
chiral
characteristics
and
process
remains
challenging.
In
this
perspective,
we
first
highlight
chirality
source
of
briefly
introduce
photo(electro)catalysis
systems.
Then,
delve
into
an
in-depth
discussion
effects
exerted
by
photo-electrochemistry
properties,
while
emphasizing
emerging
for
conversion.
Finally,
challenges
opportunities
conversion
are
prospected.
This
perspective
provides
a
comprehensive
overview
potential
which
is
beneficial
further
research
area.
Chirality,
Journal Year:
2024,
Volume and Issue:
36(7)
Published: July 1, 2024
ABSTRACT
Chirality,
the
property
of
molecules
having
mirror‐image
forms,
plays
a
crucial
role
in
pharmaceutical
and
biomedical
research.
This
review
highlights
its
growing
importance,
emphasizing
how
chiral
drugs
nanomaterials
impact
drug
effectiveness,
safety,
diagnostics.
Chiral
serve
as
precise
diagnostic
tools,
aiding
accurate
disease
detection
through
unique
biomolecule
interactions.
The
article
extensively
covers
applications
treating
cardiovascular
diseases,
CNS
disorders,
local
anesthesia,
anti‐inflammatories,
antimicrobials,
anticancer
drugs.
Additionally,
it
explores
emerging
field
nanomaterials,
highlighting
their
suitability
for
diagnostics
therapeutics,
enhancing
medical
treatments.
Small,
Journal Year:
2023,
Volume and Issue:
19(49)
Published: Aug. 17, 2023
Despite
great
advances
in
understanding
the
biological
behaviors
of
chiral
materials,
effect
chirality-configured
nanoparticles
on
tissue
regeneration-related
processes
remains
poorly
understood.
Herein,
chirality
MoS2
quantum
dots
(QDs)
is
tailored
by
functionalization
with
l-/d-penicillamine,
and
profound
effects
QDs
cellular
activities,
angiogenesis,
regeneration
are
thoroughly
investigated.
Specifically,
d-MoS2
show
a
positive
promoting
growth,
proliferation,
migration
human
umbilical
vein
endothelial
cells.
The
expression
vascular
growth
factor
(VEGF),
nitric
oxide
synthase
(eNOS),
fibroblast
(FGF)
group
substantially
up-regulated,
resulting
enhanced
tube
formation
activity.
This
distinct
phenomenon
largely
due
to
higher
internalization
efficiency
than
l-MoS2
chirality-dependent
nano-bio
interactions.
In
vivo
angiogenic
assay
shows
level
markers
newly-formed
skin
tissues
that
group,
leading
an
accelerated
re-epithelialization
improved
regeneration.
findings
angiogenesis
activity
provide
new
insights
into
nanomaterials,
which
also
opens
up
path
rational
design
nanomaterials
for
application.
Advanced Materials,
Journal Year:
2023,
Volume and Issue:
unknown
Published: Aug. 12, 2023
Abstract
Intrinsically
chiral
plasmonic
nanomaterials
exhibit
intriguing
geometry‐dependent
chiroptical
properties,
which
is
due
to
the
combination
of
features
with
geometric
chirality.
Thus,
have
become
promising
candidates
for
applications
in
biosensing,
asymmetric
catalysis,
biomedicine,
photonics,
etc.
Recent
advances
control
and
optical
tuning
intrinsically
further
opened
up
a
unique
opportunity
their
widespread
many
emerging
technological
areas.
Here,
recent
developments
are
reviewed
special
attention
given
quantitative
understanding
structure‐property
relationship.
Several
important
spectroscopic
tools
characterizing
chirality
at
both
ensemble
single‐particle
levels
also
discussed.
Three
nanomaterials,
including
enantioselective
sensing,
highlighted.
It
envisioned
that
these
advanced
studies
will
pave
way
toward
rational
design
desired
properties
diverse
applications.
