Cited by BF<sub>3</sub>·Et<sub>2</sub>O-assisted synthesis of sulfinylated spiro[5.5]trienones from biaryl ynones

Electrochemical radical-polar crossover: a radical approach to polar chemistry DOI

Zhoumei Tan,

Haonan Zhang, Kun Xu

et al.

Science China Chemistry, Journal Year: 2023, Volume and Issue: 67(2), P. 450 - 470

Published: Nov. 3, 2023

Language: Английский

Citations

Electrocatalytic three-component reactions: synthesis of tellurium-containing oxazolidinone for anticancer agents DOI

Xue‐Qi Zhou,

Haitao Tang, Fei‐Hu Cui

et al.

Green Chemistry, Journal Year: 2023, Volume and Issue: 25(13), P. 5024 - 5029

Published: Jan. 1, 2023

A new synthetic method involving electrochemical catalysis were used to synthesize various tellurium-containing oxazolidinones which showed better antitumor activity compared other oxazolidinones.

Language: Английский

Citations

Recent advances on electrochemical generation of sulfonyl radical triggered cyclization of alkene/alkynes DOI

Jiaqing Shao,

Jiang Liu, Haibo Mei

et al.

Tetrahedron, Journal Year: 2025, Volume and Issue: 173, P. 134467 - 134467

Published: Jan. 12, 2025

Language: Английский

Citations

Radical cascade cyclization of 1,n-enynes under photo/electrochemical conditions DOI

Zhenzhi Cai,

Sven Trienes, Kairui Liu

et al.

Organic Chemistry Frontiers, Journal Year: 2023, Volume and Issue: 10(22), P. 5735 - 5745

Published: Jan. 1, 2023

During the past decade, photo- and electrochemical reactions proceeding via single-electron-transfer (SET) triggered radical pathways have emerged as an indispensable strategy for efficient formation of chemical bonds.

Language: Английский

Citations

Photocatalytic C−C Cleavage of Methylenecyclobutanes for γ,δ‐Unsaturated Aldehydes by Strain Release DOI

Yan Zhang,

Chunhang Zhao,

Chanchan Ma

et al.

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 62(22)

Published: March 6, 2023

Radical additions onto olefins have surfaced as an increasingly powerful strategy for the synthesis of difunctionalized scaffolds. However, despite major advances, known approaches continue to be largely limited two manifolds, namely 1,2-difunctionalization alkenes and remote difunctionalization via hydrogen atom transfer (HAT). Herein, we describe a mechanistically distinct approach by photoinduced carbon-carbon (C-C) activation/ring-opening access γ,δ-unsaturated aldehydes from methylenecyclobutanols sulfonyl chlorides strain release. Remarkably, motif on products was easily removed another photocatalytic process, which enabled concise assembly natural product alatanone A. The synthetic utility our reflected versatile functional group tolerance, ample substrate scope, scalability. photocatalysis represents conceptually alternative existing 1,4-diversifications, with double bond remaining in thus obtained products.

Language: Английский

Citations

ipso-Cyclization of unactivated biaryl ynones leading to thio-functionalized spirocyclic enones DOI

Chada Raji Reddy,

Uprety Ajaykumar,

Amol D. Patil

et al.

Organic & Biomolecular Chemistry, Journal Year: 2023, Volume and Issue: 21(31), P. 6379 - 6388

Published: Jan. 1, 2023

Dearomative ipso -annulation of unactivated biaryl ynones using AgSCN/AgSCF 3 as the radical source in presence CAN DMSO is disclosed.

Language: Английский

Citations

Electrosynthesis of bridged or fused sulfonamides through complex radical cascade reactions: divergence in medium-sized ring formation DOI

Yan Zhang,

Zhenzhi Cai,

Chunhang Zhao

et al.

Chemical Science, Journal Year: 2023, Volume and Issue: 14(13), P. 3541 - 3547

Published: Jan. 1, 2023

Radical cascade addition is one of the most important and efficient strategies for synthesis valuable heterocycles with structural diversity complexity.

Language: Английский

Citations

Recent advances in electrooxidative radical transformations of alkynes DOI

Yan Zhang,

Zhenzhi Cai,

Svenja Warratz

et al.

Science China Chemistry, Journal Year: 2022, Volume and Issue: unknown

Published: Dec. 12, 2022

Abstract During the past few years, electrochemical oxidative reactions through radical intermediates have emerged as an environmentally-benign, powerful platform for facile formation of C–E (E = C, N, S, Se, O and Hal) bonds single-electron-transfer (SET) processes at electrodes. Functionalized unsaturated molecules unusual structural motifs can, instance, be directly constructed under exceedingly mild reaction conditions initial attack onto alkynes. This minireview highlights recent advances in electrooxidation until June 2022, with a particular focus on additions

Language: Английский

Citations

Selective Electrochemical Synthesis of 9-Aryl-10-sulfonyl Substituted Phenanthrene from Alkynes and Sulfonyl Hydrazides DOI

Haodong Tian,

Zihao Fu,

Chen Li

et al.

Organic Letters, Journal Year: 2022, Volume and Issue: 24(50), P. 9322 - 9326

Published: Dec. 9, 2022

An efficient electrochemical synthesis of sulfonated phenanthrenes via the reaction internal alkynes with sulfonyl hydrazides has been established. The protocol does not require a metal catalyst or external oxidants, providing green and mild route to functionalized phenanthrenes. Moreover, compatibility various functional groups decagram-scale experimental conditions demonstrate practicality strategy.

Language: Английский

Citations

Electrochemical Selenium-Catalyzed N,O-Difunctionalization of Ynamides: Access to Polysubstituted Oxazoles DOI

Jun‐Qi Zhang,

Chunjiao Shen,

Shihao Shuai

et al.

Organic Letters, Journal Year: 2022, Volume and Issue: 24(51), P. 9419 - 9424

Published: Dec. 21, 2022

A green and efficient approach for the difunctionalization of ynamides by merging electrochemical organoselenium-catalyzed processes is described. This strategy features mild reaction conditions, broad functional group tolerance high atom-economy, requires no external chemical oxidant. Hence, we provide a sustainable alternative synthesis polysubstituted oxazoles.

Language: Английский

Citations