European Journal of Organic Chemistry,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 2, 2024
Abstract
Herein,
we
present
an
efficient
strategy
for
the
synthesis
of
spiro(indenyl)cyclohexadienones
through
radical‐promoted
reaction
2‐alkynyl
biaryls
with
sodium
sulfinates
under
electrochemical
conditions.
The
involves
sulfonylation
and
dearomative
ipso‐
cyclisation
in
a
domino
fashion.
This
approach
features
use
readily
accessible
precursors,
wide
functional
group
tolerance
external
oxidant‐free
practicality
method
was
also
illustrated
by
scale‐up
further
diversification
product.
Asian Journal of Organic Chemistry,
Journal Year:
2023,
Volume and Issue:
12(8)
Published: July 20, 2023
Abstract
In
terms
of
pharmaceuticals
and
biological
applications,
synthesis
complex
organic
molecules
is
a
significant
fast‐developing
area.
this
context,
electrosynthesis
an
alternative
way
to
the
traditional
methods
for
chemo‐,
regio‐,
stereoselective
syntheses.
Electro‐organic
reactions
occur
at
room
temperature
normal
pressure,
through
transferring
electrons.
It
has
been
found
that
mild
approach
preparing
electrophilic
substrates,
bases,
nucleophiles
in
situ
,
from
highly
stable
low‐level
reagents;
which
can
be
further
applied
make
heterocycles
more
accessible.
While
several
promising
exist,
multi‐component
(MCRs)
have
drawn
much
attention
both
academia
industry
worldwide,
since
they
are
cost‐efficient
environmentally
friendly.
Combining
MCRs
produced
great
strategy
field
research.
This
review
focuses
on
recent
advances
electrochemical
heterocyclic
compounds
via
reactions,
reported
between
2015
March
2023.
ACS Organic & Inorganic Au,
Journal Year:
2024,
Volume and Issue:
4(5), P. 471 - 484
Published: June 21, 2024
The
electrochemical
oxidation
of
amines
to
nitriles
and
imines
represents
a
critical
frontier
in
organic
electrochemistry,
offering
sustainable
pathway
these
valuable
compounds.
Nitriles
are
pivotal
various
industrial
applications,
including
pharmaceuticals,
agrochemicals,
materials
science.
This
review
encapsulates
the
recent
advancements
electrooxidation
process,
emphasizing
mechanistic
understanding,
electrode
material
innovations,
optimization
reaction
conditions,
exploration
solvent
electrolyte
systems.
Additionally,
addresses
operational
parameters
that
significantly
affect
such
as
current
density,
temperature,
surface,
insights
into
their
for
enhanced
performance.
By
providing
comprehensive
view
state
prospects
amine
imines,
this
aims
inspire
further
development,
innovation,
research
promising
area
green
chemistry.
Beilstein Journal of Organic Chemistry,
Journal Year:
2025,
Volume and Issue:
21, P. 770 - 797
Published: April 16, 2025
In
this
review,
we
describe
recent
advances
in
electrochemical
green
methods
for
the
synthesis
of
various
organophosphorus
compounds
through
formation
phosphorus–carbon,
phosphorus–nitrogen,
phosphorus–oxygen,
phosphorus–sulfur,
and
phosphorus–selenium
bonds.
The
impact
different
electrodes
is
also
discussed
matter.
Graphite,
platinum,
RVC,
nickel
have
been
used
extensively
compounds.
made
method
a
promising
preparing
structures.
This
review
an
introduction
to
encourage
scientists
use
electrosynthesis
as
green,
precise,
low-cost
prepare
phosphorous
ACS Omega,
Journal Year:
2024,
Volume and Issue:
9(12), P. 14198 - 14209
Published: March 14, 2024
In
this
work,
a
novel,
green,
and
atom-efficient
method
for
the
synthesis
of
tetrahydro-β-carboline
derivatives
using
electrochemistry
(EC)
in
deep
eutectic
solvents
(DESs)
was
reported.
The
EC
reaction
conditions
were
optimized
to
achieve
highest
yield.
experimental
design
also
perform
two-step,
one-pot
reaction,
thereby
time,
workup
procedure,
needed
all
reduced.
new
approach
achieved
our
strategy
as
served
decrease
time
eliminate
use
hazardous
catalysts,
lower
energy
required
targeted
compounds.
On
other
side,
DESs
used
situ
electrolytes,
noninflammable
green
solvents.
scope
investigated
different
aromatic
aldehydes.
Finally,
scalability
gram-scale
that
afforded
product
an
excellent
ACS Omega,
Journal Year:
2025,
Volume and Issue:
unknown
Published: May 1, 2025
The
N-to-P
substitution
in
nonfullerene
acceptors
(NFAs)
is
an
intriguing
strategy
to
address
environmental
and
economic
concerns
associated
with
the
cyano
(-C≡N)
group.
In
this
study,
we
performed
a
comprehensive
computational
investigation
of
end
groups
Y6
molecule,
benchmark
NFA
for
organic
photovoltaics
(OPV).
Using
density
functional
theory
(DFT),
time-dependent
DFT
(TD-DFT),
molecular
dynamics,
analyzed
effects
on
electronic
structure
intermolecular
interactions.
Our
results
reveal
significant
changes
intramolecular
properties
depending
P
atom's
position.
P≡C
bond
longer
than
N≡C
bond,
enhancing
delocalization,
reducing
both
fundamental
optical
gaps,
improving
light
absorption
exciton
dissociation.
However,
incorporation
reduces
quadrupole
moment,
slightly
weakening
interactions
coupling.
Despite
this,
electron
transfer
rate
remains
stable
due
compensation
effect
reorganization
energy.
Overall,
our
findings
suggest
that
enhances
key
optoelectronic
Y6,
potentially
benefiting
OPV
performance.
This
study
provides
valuable
insights
into
feasibility
modification
electronics.
