Current Green Chemistry,
Journal Year:
2024,
Volume and Issue:
12(2), P. 85 - 116
Published: Sept. 26, 2024
In
the
realm
of
synthetic
organic
chemistry,
environmentally
friendly
manipulation
small
molecules
has
gained
prominence.
One
particularly
promising
approach
is
electrochemical
synthesis,
which
offers
a
green
and
sustainable
alternative
to
using
hazardous
toxic
redox
reagents.
By
harnessing
electric
current
from
renewable
sources
like
sunlight
or
wind,
synthesis
emerges
as
viable
replacement
for
conventional
methods.
This
review
article
provides
comprehensive
exploration
method,
delving
into
its
background
applications
in
synthesizing
transforming
various
molecules,
including
sulfoximines,
isoxazolines,
benzimidazoles,
more.
aims
shed
light
on
potential
greener
more
way
conducting
transformations.
Asian Journal of Organic Chemistry,
Journal Year:
2023,
Volume and Issue:
12(8)
Published: July 20, 2023
Abstract
In
terms
of
pharmaceuticals
and
biological
applications,
synthesis
complex
organic
molecules
is
a
significant
fast‐developing
area.
this
context,
electrosynthesis
an
alternative
way
to
the
traditional
methods
for
chemo‐,
regio‐,
stereoselective
syntheses.
Electro‐organic
reactions
occur
at
room
temperature
normal
pressure,
through
transferring
electrons.
It
has
been
found
that
mild
approach
preparing
electrophilic
substrates,
bases,
nucleophiles
in
situ
,
from
highly
stable
low‐level
reagents;
which
can
be
further
applied
make
heterocycles
more
accessible.
While
several
promising
exist,
multi‐component
(MCRs)
have
drawn
much
attention
both
academia
industry
worldwide,
since
they
are
cost‐efficient
environmentally
friendly.
Combining
MCRs
produced
great
strategy
field
research.
This
review
focuses
on
recent
advances
electrochemical
heterocyclic
compounds
via
reactions,
reported
between
2015
March
2023.
Organic Chemistry Frontiers,
Journal Year:
2023,
Volume and Issue:
11(2), P. 597 - 630
Published: Nov. 23, 2023
This
review
highlights
the
recent
progress
in
electrochemical
difunctionalization
of
alkenes
and
alkynes
involving
C–S/Se
bond
formation
to
access
organochalcogen
frameworks.
Organic Letters,
Journal Year:
2024,
Volume and Issue:
26(25), P. 5263 - 5268
Published: June 14, 2024
A
green
and
sustainable
electrochemical
oxidative
cyclization
of
enaminones
with
thioamides
under
metal-
oxidant-free
conditions
has
been
developed,
providing
an
efficient
approach
for
thiazole
synthesis.
Furthermore,
1,2,4-thiadiazoles
can
be
selectively
accessed
via
the
dimerization
in
absence
enaminones.
Advanced Synthesis & Catalysis,
Journal Year:
2024,
Volume and Issue:
366(6), P. 1220 - 1268
Published: Jan. 22, 2024
Abstract
Elaborated
molecular
architectures,
specifically
those
bearing
one
or
more
carbon
stereocenters,
stand
as
an
important
class
of
carbocyclic
and
heterocyclic
frameworks
because
they
are
frequently
occurring
core
structures
in
numerous
natural
products
biologically
active
pharmaceutical
molecules.
Over
the
past
few
decades,
development
versatile
synthetic
approaches
via
cascade
cyclization
reactions
1,6‐enynes
for
construction
a
series
fused
spiro
compounds
has
been
focus
great
deal
research
initiatives.
These
synthesis
strategies
peculiarly
fascinating
context
assembly
wide
array
molecules,
products,
agrochemicals,
functional
materials.
In
this
review,
recent
developments
transformations
with
diverse
coupling
reagents
summarized
since
2018,
which
could
be
divided
into
five
categories:
1)
Introduction;
2)
Transition
metal
catalyzed
1,6‐enynes;
3)
Metal‐free
4)
Visible‐light‐induced
5)
Electrocatalytic
1,6‐enynes.
Chemical Science,
Journal Year:
2024,
Volume and Issue:
15(8), P. 2827 - 2832
Published: Jan. 1, 2024
Efficient
control
over
several
possible
reaction
pathways
of
free
radicals
is
the
chemical
basis
their
highly
selective
transformations.
Among
various
competing
pathways,
sulfonimidyl
generated
from
electrolysis
2-alkynylbenzenesulfonamides
undergo
cascade
migratory
or
Organic & Biomolecular Chemistry,
Journal Year:
2024,
Volume and Issue:
22(25), P. 5052 - 5086
Published: Jan. 1, 2024
1,2/1,1-Difunctionalization
of
alkynes
(cascade
C–C
and
C–O
bond
formations)
serves
as
one
the
reliable
methods
for
synthesis
numerous
chemical
architectures.
