Angewandte Chemie International Edition,
Journal Year:
2022,
Volume and Issue:
62(5)
Published: Nov. 1, 2022
Abstract
As
a
consequence
of
rapid
industrialization
throughout
the
world,
various
environmental
pollutants
have
begun
to
accumulate
in
water,
air,
and
soil.
This
endangers
ecological
environment
earth,
remediation
has
become
an
immediate
priority.
Among
techniques,
piezocatalytic
which
uniquely
take
advantage
piezoelectric
effect,
attracted
much
attention.
Piezoelectric
effects
allow
pollutant
degradation
directly,
while
also
enhancing
photocatalysis
by
reducing
recombination
photogenerated
carriers.
In
this
Review,
we
provide
comprehensive
summary
recent
developments
techniques
for
remediation.
The
origin
effect
as
well
classification
materials
their
application
are
systematically
summarized.
We
analyze
potential
underlying
mechanisms.
Finally,
urgent
problems
future
development
discussed.
Advanced Functional Materials,
Journal Year:
2020,
Volume and Issue:
30(48)
Published: Sept. 9, 2020
Abstract
Piezoelectric‐based
catalysis
that
relies
on
the
charge
energy
or
separation
efficiency
of
carriers
has
attracted
significant
attention.
The
piezo‐potential
induced
by
strain
stress
can
induce
a
giant
electric
field,
which
been
demonstrated
to
be
an
effective
means
for
shifting
transferring
electrons
and
holes.
In
recent
years,
intense
efforts
have
made
in
this
subject,
research
mainly
focussed
two
aspects:
i)
Alteration
surface
piezocatalysis;
ii)
photo‐generated
catalytic
activity
enhancement
integrated
piezoelectric
semiconductor
coupled
system
composed
piezoelectrics
semiconductors.
Systematically
summarizing
advances
above
aspects
is
helpful
context
deepening
understanding
relevant
issues
developing
new
ideas
piezoelectric‐based
catalysis.
review,
comprehensive
summary
piezocatalysis
piezo‐photocatalysis
provided.
transfer
behaviors
mechanisms
over
large
variety
piezocatalysts
piezo‐photocatalysts
are
systematically
analyzed.
addition,
types
mechanical
energy,
strategies
enhancing
piezocatalysis,
advanced
applications
discussed.
Finally,
promising
development
directions
piezo‐photocatalysis,
such
as
materials,
assembly
forms,
future
proposed.
ChemSusChem,
Journal Year:
2021,
Volume and Issue:
14(10), P. 2145 - 2162
Published: April 9, 2021
In
recent
years,
mechanochemistry
has
been
growing
into
a
widely
accepted
alternative
for
chemical
synthesis.
addition
to
their
efficiency
and
practicality,
mechanochemical
reactions
are
also
recognized
sustainability.
The
association
between
Green
Chemistry
often
originates
from
the
solvent-free
nature
of
most
protocols,
which
can
reduce
waste
production.
However,
satisfies
more
than
one
Principles
Chemistry.
this
Review
we
will
present
series
examples
that
clearly
illustrate
how
significantly
contribute
fulfillment
in
holistic
manner.
Journal of the American Chemical Society,
Journal Year:
2020,
Volume and Issue:
142(36), P. 15205 - 15218
Published: Aug. 18, 2020
Ferroelectric
materials
have
a
variety
of
technological
applications,
as
transducers,
capacitors,
sensors,
etc.
Great
interest
in
molecular
ferroelectrics
has
emerged
because
their
structural
flexibility,
tunability,
and
homochirality.
However,
the
discoveries
are
not
abundant.
The
lack
chemical
design
is
main
challenge
realizing
new
ferroelectrics.
Consequently,
approaches,
including
ideas
introducing
quasi-spherical
theory,
homochirality,
H/F
substitution,
been
developed
recently.
Through
these
advanced
methodologies,
wide
range
were
successfully
synthesized,
changing
blind
search
into
targeted
design.
In
this
Perspective,
we
aim
to
provide
insight
fundamental
chemistry
physics
propose
concept
"ferroelectrochemistry",
concerned
with
performance
optimization
from
point
view.
We
start
basic
theories
used
modification
structures
for
ferroelectrics,
such
theory.
After
that,
focus
on
fundamentals
homochirality
perspective
advantages
homochiral
molecule
within
scope
Further,
explore
another
strategy,
an
analogue
H/D
isotope
effect.
introduction
F
atom
usually
does
change
polar
group
but
may
induce
minor
disruption
that
enhances
physical
properties
Curie
temperature
spontaneous
polarization.
hope
our
comprehensive
studies
strategies
build
up
enrich
content
ferroelectrochemistry.
ACS Applied Nano Materials,
Journal Year:
2020,
Volume and Issue:
3(2), P. 1063 - 1079
Published: Jan. 21, 2020
Ferro-,
piezo-,
and
pyroelectric
materials
are
emerging
as
potential
candidates
for
converting
various
forms
of
primary
energy
from
the
ambient
environment
(e.g.,
sunlight,
mechanical,
thermal
energy)
into
secondary
chemical
energy).
Despite
relatively
short
investigation
time,
much
progress
has
been
made
related
to
this
field.
This
review
covers
fundamental
principles
coupling
ferro-,
effects
with
different
catalytic
reactions;
crucial
role
a
polarization-induced
internal
electric
field
in
charge
separation
transport
these
is
discussed.
We
particularly
focus
on
recent
notable
examples
using
three
types
nanostructured
variety
applications
fields
renewable
production
water
splitting
CO2
reduction),
environmental
remediation
organic
pollutant
decontamination),
synthesis
selective
growth/deposition
synthesis).
Finally,
we
conclude
by
proposing
critical
challenges
future
perspectives
developing
nanomaterial-based
catalysts
efficient
harvesting.
ACS Catalysis,
Journal Year:
2020,
Volume and Issue:
10(15), P. 8344 - 8394
Published: May 27, 2020
The
extraordinary
impact
of
metal-based
complexes
on
synthetic
methods
is
still
recognized
nowadays,
and
attempts
are
currently
undertaken
to
further
extend
the
use
metal-assisted
chemistry
environmentally
friendly
processes
within
strongly
invoked
green
paradigm.
In
recent
years,
mechanochemistry
seems
provide
attractive
responses
with
processing
having
origins
lost
in
mists
time.
Focusing
panorama
organic
synthesis,
this
Review
highlights
some
recently
developed
mechanochemical
reactions
introduce
reader
into
fascinating,
quite
unexplored
world
mechanochemistry.
Advanced Synthesis & Catalysis,
Journal Year:
2021,
Volume and Issue:
363(5), P. 1246 - 1271
Published: Jan. 21, 2021
Abstract
Mechanochemical
reactions
by
milling,
grinding
or
other
types
of
mechanical
action
have
emerged
as
a
salient
green
approach
because
its
wide
applications
towards
academic
and
industrial
chemical
communities
in
sustainable
solvent‐free/solvent‐less
processes.
Liquid‐assisted
(LAG)
an
extension
traditional
solvent‐free
mechanochemical
techniques
which
small
amount
liquid
is
used
additive
to
enhance
and/or
control
reactivity,
has
been
fruitfully
applied
the
screening
inclusion
compounds,
cocrystals,
salts,
solvates,
polymorphs.
However,
utilization
this
important
technique
synthesis
pharmaceutically
biologically
relevant
targets
was
not
adequately
investigated.
This
review
article
summarizes
overview
latest
development
LAG
approaches
active
pharmaceutical
ingredients
(API)
drug‐like
fragments,
highlights
superiority
versus
conventional
syntheses.
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