Recent progress in lanthanide-based metal halide perovskites: Synthesis, properties, and applications DOI Creative Commons
Tuhin Samanta, Nagaraju Mukurala, Noolu Srinivasa Manikanta Viswanath

et al.

Optical Materials X, Journal Year: 2023, Volume and Issue: 18, P. 100238 - 100238

Published: May 1, 2023

Metal halide perovskites (MHPs) have recently attracted significant interest, owing to their excellent optoelectronic properties and diverse applications, including photovoltaics, solid-state lighting emitting diodes (LEDs), other applications. However, the toxic nature of lead-based MHPs, lanthanide-based MHPs emerged as an alternative, leading new opportunities for emerging such in near-infrared (NIR) imaging, NIR cameras, white LEDs, information encryption. Moreover, lanthanide doping significantly enhances stability optical MHPs. In this review, we attempted overview state-of-the-art synthesis strategies investigate structural, Furthermore, several applications solar cells, temperature sensors are discussed along with outlooks future directions.

Language: Английский

Recent progress in lanthanide ions doped inorganic metal halide perovskites DOI
Yiyan Zhang, Tianyu Zhao, Guanying Chen

et al.

Journal of Rare Earths, Journal Year: 2023, Volume and Issue: 42(2), P. 237 - 250

Published: April 10, 2023

Language: Английский

Citations

26
Novel dual-modification strategy using Ce-containing compounds toward high-performance flexible perovskite solar cells DOI

Zijun Yi,

Bo Xiao, Xin Li

et al.

Nano Energy, Journal Year: 2023, Volume and Issue: 109, P. 108241 - 108241

Published: Jan. 29, 2023

Language: Английский

Citations

25
Perovskite Solar Cells with Extremely High 24.63% Efficiency through Design of Double Electron Transport Layers and Double Luminescent Converter Layers DOI
Bin Liu, Yuqi Wang,

Shuhang Bian

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(34)

Published: Feb. 20, 2024

Abstract Introduction of fluorescent down‐conversion layer inside perovskite solar cells (PSCs) can highly improve the ultraviolet response devices and light stability. However, such a device is usually confronted with problem inter‐diffusion absorber layer, which severely limits its further development. To address this problem, herein, work employs an interfacial dual electron transport layers (ETLs) strategy, sandwiching Cd‐CsPbCl 3 :Mn 2+ luminescent quantum dots within gap ETLs, not only reduces interface energy level offset, but also improves nucleation crystallization kinetics films prevents their diffusion to layer. As result, efficient synergy effect effectively elevates both open‐circuit voltage fill factor PSCs, reaching maximum values 1.181 V 81.14%, respectively, finally delivering progressively increased power conversion efficiency (PCE) 24.32% significantly improved response, adopts strategy outside obtains PCE 24.63%, best for various cells. This opens new door development stable photoluminescence PSCs.

Language: Английский

Citations

13
Lanthanide Ion‐Doped Perovskite Nanocrystals in Electroluminescent Device DOI

Jia‐Lin Pan,

Yan‐Jun Yu,

Ya‐Kun Wang

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(36)

Published: April 10, 2024

Abstract Lanthanide ions doped in perovskite (LIDP) nanocrystals (NCs) provide an effective way to utilize the emission of lanthanide metals a solution‐processable way, combining theoretical photoluminance quantum yield (PLQY) ≈200%. To advantages, LIDP‐NCs have inspired studies exploring fundamental physics energy transfer, including up‐conversion or down‐conversion process, and optoelectronic applications solar cells white light‐emitting didoes. This review broadens scope LIDP nanocrystal matrix semiconductors electroluminescence devices near‐infrared (NIR) range (>900 nm). A research is summarized on synergistic effect region, discuss from perspective fabrication lanthanide‐based electroluminescent using materials as matrix. The multiple optical transitions, bandgap tunability, quantum‐cutting tutorial understanding are started. details synthesizing aim lay foundation for preparing NIR with high efficiency application value then illustrated. scientific issues that limit performance NCs‐based potential strategies future development material focused on.

Language: Английский

Citations

12
Bottom‐Up Defect Modification Through Oily‐Allicin Modified Buried Interface Achieving Highly Efficient and Stable Perovskite Solar Cells DOI

Xinmeng Zhuang,

Donglei Zhou,

Yanrun Jia

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: July 18, 2024

The buried interface properties of the perovskite solar cells (PSCs) play a crucial role in power conversion efficiency (PCE) and operational stability. metal-oxide/perovskite heterogeneous interfaces are highly defective cause serious ion migration. However, unexposed bottom simultaneous stabilization grain boundaries receive less attention effective solutions. To tackle this problem, solid-liquid strategy is employed by introducing oily-additive allicin at to passivate shallow (V

Language: Английский

Citations

11
Synergistic Integration of Halide Perovskite and Rare‐Earth Ions toward Photonics DOI Open Access
Jiayu Sun,

Hongyang Fu,

Haitong Jing

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 13, 2025

Abstract Halide perovskites (HPs), emerging as a noteworthy class of semiconductors, hold great promise for an array optoelectronic applications, including anti‐counterfeiting, light‐emitting diodes (LEDs), solar cells (SCs), and photodetectors, primarily due to their large absorption cross section, high fluorescence efficiency, tunable emission spectrum within the visible region, tolerance lattice defects, well adaptability solution‐based fabrication processes. Unlike luminescent HPs with band‐edge emission, trivalent rare‐earth (RE) ions typically emit low‐energy light through intra‐4f optical transitions, characterized by narrow spectra long lifetimes. When fused, cooperative interactions between REs endow resulting binary composites not only properties inherited from parent materials but also introduce new attributes unattainable either component alone. This review begins fundamental characteristics REs, followed particular focus on impact electronic structures associated energy transfer The advanced synthesis methods utilized prepare HPs, RE‐doped compounds, are overviewed. Furthermore, potential applications summarized across diverse domains, high‐fidelity anticounterfeiting, bioimaging, LEDs, photovoltaics, photodetection, photocatalysis, conclude remaining challenges future research prospects.

Language: Английский

Citations

1
Inhibiting Interfacial Diffusion in Heterojunction Perovskite Solar Cells by Replacing Low‐Dimensional Perovskite with Uniformly Anchored Quaternized Polystyrene DOI
Congcong Tian,

Anxin Sun,

Jianghu Liang

et al.

Small, Journal Year: 2023, Volume and Issue: 19(32)

Published: April 17, 2023

Surface heterojunction has been regarded as an effective method to improve the device efficiency of perovskite solar cells. Nevertheless, durability different under thermal stress is rarely investigated and compared. In this work, benzylammonium chloride benzyltrimethylammonium are utilized construct 3D/2D 3D/1D heterojunctions, respectively. A quaternized polystyrene synthesized a three-dimensional perovskite/amorphous ionic polymer (3D/AIP) heterojunction. Due migration volatility organic cations, severe interfacial diffusion found among in which quaternary ammonium cations 1D structure less volatile mobile than primary 2D structure. 3D/AIP remains intact due strong bond anchoring at interface ultra-high molecular weight AIP. Furthermore, dipole layer formed by AIP can further reduce voltage loss caused nonradiative recombination 0.088 V. Therefore, devices based on achieve champion power conversion 24.27% maintain 90% its initial after either aging for 400 h or wet 3000 h, showing great promise polymer/perovskite towards real applications.

Language: Английский

Citations

18
Smart Dope: A Self‐Driving Fluidic Lab for Accelerated Development of Doped Perovskite Quantum Dots DOI Creative Commons
Fazel Bateni, Sina Sadeghi, Negin Orouji

et al.

Advanced Energy Materials, Journal Year: 2023, Volume and Issue: 14(1)

Published: Nov. 12, 2023

Abstract Metal cation‐doped lead halide perovskite (LHP) quantum dots (QDs) with photoluminescence yields (PLQYs) higher than unity, due to cutting phenomena, are an important building block of the next‐generation renewable energy technologies. However, synthetic route exploration and development highest‐performing QDs for device applications remain challenging. In this work, Smart Dope is presented, which a self‐driving fluidic lab (SDFL), accelerated synthesis space autonomous optimization LHP QDs. Specifically, multi‐cation doping CsPbCl 3 using one‐pot high‐temperature chemistry reported. continuously synthesizes multi‐cation‐doped high‐pressure gas‐liquid segmented flow format enable continuous experimentation minimal experimental noise at reaction temperatures up 255°C. offers multiple functionalities, including mechanistic studies through digital twin QD modeling, closed‐loop discovery, on‐demand manufacturing high‐performing Through these developments, autonomously identifies optimal Mn‐Yb co‐doped PLQY 158%, highest reported value class date. illustrates power SDFLs in accelerating discovery emerging advanced materials.

Language: Английский

Citations

18
Interfacial Engineering of Au@Nb2CTx-MXene Modulates the Growth Strain, Suppresses the Auger Recombination, and Enables an Open-Circuit Voltage of over 1.2 V in Perovskite Solar Cells DOI
Shuainan Liu, Donglei Zhou,

Xinmeng Zhuang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2023, Volume and Issue: 15(3), P. 3961 - 3973

Published: Jan. 13, 2023

Defects at the interface of charge transport layers can cause severe accumulation and poor transferability, which greatly affect efficiency stability stannic oxide (SnO2)-based perovskite solar cells (PSCs). Herein, a new type MXene (Nb2CTx-MXene) is applied to SnO2 passivate interfacial defects promote transport. Nb2CTx-MXene in PSCs realizes role boosting conductivity, reducing tin vacancies interstitial void layer, decreasing defect density, aligning bandgap. Afterward, decorated with gold nanospheres, has ability modulate tensile strain perovskites suppress Auger recombination. Eventually, Au@Nb2CTx-MXene-modified device yields an excellent power conversion (PCE) 23.78% relatively high open-circuit voltage 1.215 V (Eg ∼ 1.60 eV). The unencapsulated devices maintain 90% their initial PCE values after storage air relative humidity 40% for 1000 h remain above 80% operation maximum point 500 under 1 sun illumination. Our work provides avenue fabricate high-efficiency stable adapting commercial development.

Language: Английский

Citations

17
[Gd-Ho-Dy]:CsPbI1.8Br1.2 stable perovskite material as an absorber layer in photovoltaic devices, charge storage electrode, and an efficacious OER/HER catalyst DOI
Shaan Bibi Jaffri, Khuram Shahzad Ahmad, Isaac Abrahams

et al.

Solar Energy, Journal Year: 2023, Volume and Issue: 262, P. 111800 - 111800

Published: June 19, 2023

Language: Английский

Citations

17