Abstract
Imidazoheterocycles
have
extensive
applications
in
the
pharmaceutical
industry
and
agrochemicals.
A
comprehensive
overview
has
been
provided
on
current
advancements
electrochemical
functionalization
of
imidazo‐fused
heterocycles,
which
classified
into
ten
different
types
reactions.
Electrochemical
synthesis
emerged
as
a
highly
effective
method
for
producing
organic
molecules,
especially
context
sustainable
development.
Employing
electrons
traceless
oxidant,
several
C−H
reactions
heterocycles
achieved
at
either
C3
or
C5
positions.
Electrons
may
serve
reducing
agent
to
synthesize
pyridine
rings
that
are
partially
fully
saturated
imidazo[1,2‐
]pyridines.
The
purpose
review
is
attract
interest
scientific
community
promote
additional
research
imidazoheterocycles
using
methods.
Organic Letters,
Journal Year:
2021,
Volume and Issue:
23(8), P. 2976 - 2980
Published: March 29, 2021
A
general
and
metal-free
visible-light-induced
decarboxylative
arylation
procedure
at
room
temperature
was
described
for
the
construction
of
acylated
heterocyclic
derivatives,
such
as
benzimidazo/indolo[2,1-a]isoquinolin-6(5H)-ones,
aroylazaspiro[4.5]trienones,
thioflavones,
so
on.
This
practical
conducted
by
using
2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile
(4CzIPN)
a
photocatalyst
under
mild
conditions,
which
avoided
use
an
additional
base,
traditional
heating,
metal
reagents.
Green Chemistry,
Journal Year:
2021,
Volume and Issue:
23(10), P. 3677 - 3682
Published: Jan. 1, 2021
A
metal-free
photocatalytic
strategy
for
the
preparation
of
thiocyanated
heterocycles
from
inexpensive
NH4SCN
has
been
developed
using
carbon
nitride
(g-C3N4)
as
a
general
heterogeneous
catalyst.
Green Chemistry,
Journal Year:
2023,
Volume and Issue:
25(20), P. 7971 - 7977
Published: Jan. 1, 2023
Alkyl
diacyl
peroxides
were
demonstrated
to
be
efficient
alkylating
reagents
for
the
visible-light-induced
4CzIPN-catalyzed
direct
C–H
alkylation
of
N
-heteroaromatics.
Chemical Society Reviews,
Journal Year:
2023,
Volume and Issue:
52(7), P. 2391 - 2479
Published: Jan. 1, 2023
The
metal-free
C–H
functionalisation
is
providing
environmentally
benign,
cost-effective,
sustainable
catalytic
systems.
Comprehensive
developments
of
various
reactions
are
the
focal
point
this
review.
The Journal of Organic Chemistry,
Journal Year:
2021,
Volume and Issue:
86(13), P. 9055 - 9066
Published: June 23, 2021
A
visible-light-induced
decarboxylation
reaction
was
developed
for
the
synthesis
of
alkylated
benzimidazo[2,1-a]isoquinoline-6(5H)-ones
and
indolo[2,1-a]isoquinolin-6(5H)-ones
under
metal-free
conditions.
Impressively,
metal
catalysts
traditionally
volatile
organic
solvents
could
be
effectively
avoided.
The Journal of Organic Chemistry,
Journal Year:
2024,
Volume and Issue:
89(5), P. 2996 - 3009
Published: Feb. 15, 2024
An
efficient
and
highly
regioselective
C6-phosphorylation
protocol
for
pyrrolo[2,3-d]pyrimidine
(7-DAP)
derivatives
with
various
H-phosphine
oxides
induced
by
visible
light
at
room
temperature
is
described
the
first
time.
This
has
been
successfully
achieved
combination
of
Na2-eosin
Y
as
a
photocatalyst
LPO
an
oxidant
under
transition
metal-
additive-free
conditions.
The
broad
substrate
scope,
good
functional
group
tolerance,
excellent
regioselectivity,
air
tolerant
conditions
make
this
process
favorable
modification
scaffold
enrich
phosphorylated
7-DAP
compounds
further
biological
evaluation.
Chinese Journal of Organic Chemistry,
Journal Year:
2021,
Volume and Issue:
41(12), P. 4661 - 4661
Published: Jan. 1, 2021
N-Hydroxyphthalimide
(NHP)
esters
are
easily
available,
stable,
inexpensive,
and
highly
photoactive
compounds,
which
derived
from
the
corresponding
carboxylic
acids.In
recent
years,
application
of
NHP
in
photocatalytic
decarboxylative
reactions
has
captured
huge
attention.Herein,
vigorous
development
alkylation
using
alkyl
as
alkylating
reagents
is
summarized
based
on
classification
photocatalysts.
Chemical Synthesis,
Journal Year:
2021,
Volume and Issue:
unknown
Published: Jan. 1, 2021
Chemical
Synthesis
is
an
open
access
peer-reviewed
journal
publishing
original
research
involving
all
areas
of
the
chemical
sciences.
The
aims
to
be
premier
resource
seminal
and
insightful
showcases
for
researchers
in
both
academia
industry,
providing
a
platform
inspiration
future
chemistry.
intends
serve
as
preeminent
international
chemistry
has
ambition
among
first
choices
chemists
publication
their
discoveries.
