Tinkering with Mechanochemical Tools for Scale Up DOI Creative Commons
Javier F. Reynes, Valerio Isoni, Felipe Garcı́a

et al.

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 62(44)

Published: April 28, 2023

Mechanochemistry provides an environmentally benign platform to develop more sustainable chemical processes by limiting raw materials, energy use, and waste generation while using physically smaller equipment. A continuously growing research community has steadily showcased examples of beneficial mechanochemistry applications at both the laboratory preparative scale. In contrast solution-based chemistry, mechanochemical have not yet been standardized, thus scaling up is still a nascent discipline. The purpose this Minireview highlight similarities, differences challenges various approaches that successfully applied for range scales. We hope provide discussion starting point those interested in further developing commercial use and/or industrialisation.

Language: Английский

Mechanochemistry for Synthesis DOI
Tomislav Friščić, Cristina Mottillo, Hatem M. Titi

et al.

Angewandte Chemie International Edition, Journal Year: 2019, Volume and Issue: 59(3), P. 1018 - 1029

Published: July 11, 2019

Abstract Mechanochemical solvent‐free reactions by milling, grinding or other types of mechanical action have emerged as a viable alternative to solution chemistry. Mechanochemistry offers not only possibility eliminate the need for bulk solvent use, and reduce generation waste, but it also unlocks door different reaction environment in which synthetic strategies, molecules previously accessible solution, can be achieved. This Minireview examines potential mechanochemistry chemical materials synthesis, providing cross‐section recent developments using ball milling formation based on covalent coordination bonds.

Language: Английский

Citations

862

Main group mechanochemistry: from curiosity to established protocols DOI Creative Commons
Davin Tan, Felipe Garcı́a

Chemical Society Reviews, Journal Year: 2019, Volume and Issue: 48(8), P. 2274 - 2292

Published: Jan. 1, 2019

In the last few decades, mechanochemistry has become rapidly established as a powerful tool enabling environmentally-benign and sustainable chemical syntheses. Not only have these techniques been demonstrated viable alternatives to traditional solution-based syntheses, but they also received attention for their ability enable new reactivity "unlocking" novel compounds inaccessible by conventional methods. Reflecting rising popularity of mechanochemistry, many excellent reviews highlighting its benefits recently published. Whilst scope most focuses on organic chemistry, transition-metal catalysis, porous framework materials, coordination supramolecular synthesis, addressed use mechanochemical ball milling synthesis containing s- p-block elements. This tutorial review turns spotlight towards research in field inorganic main group significant advantages that solid-state reactions often possess, potential drive development greener methodologies within modern arena.

Language: Английский

Citations

474

Sustainability Assessment of Mechanochemistry by Using the Twelve Principles of Green Chemistry DOI
Karen J. Ardila‐Fierro, José G. Hernández

ChemSusChem, Journal Year: 2021, Volume and Issue: 14(10), P. 2145 - 2162

Published: April 9, 2021

In recent years, mechanochemistry has been growing into a widely accepted alternative for chemical synthesis. addition to their efficiency and practicality, mechanochemical reactions are also recognized sustainability. The association between Green Chemistry often originates from the solvent-free nature of most protocols, which can reduce waste production. However, satisfies more than one Principles Chemistry. this Review we will present series examples that clearly illustrate how significantly contribute fulfillment in holistic manner.

Language: Английский

Citations

471

Redox reactions of small organic molecules using ball milling and piezoelectric materials DOI
Koji Kubota, Yadong Pang, Akira Miura

et al.

Science, Journal Year: 2019, Volume and Issue: 366(6472), P. 1500 - 1504

Published: Dec. 20, 2019

Over the past decade, photoredox catalysis has harnessed light energy to accelerate bond-forming reactions. We postulated that a complementary method for redox-activation of small organic molecules in response applied mechanical could be developed through piezoelectric effect. Here, we report agitation materials via ball milling reduces aryl diazonium salts. This mechanoredox system can arylation and borylation reactions under mechanochemical conditions.

Language: Английский

Citations

438

Mechanochemistry of Gaseous Reactants DOI
Carsten Bolm, José G. Hernández

Angewandte Chemie International Edition, Journal Year: 2018, Volume and Issue: 58(11), P. 3285 - 3299

Published: Nov. 12, 2018

Abstract In recent years, the application of mechanical energy to chemical systems has repeatedly proven beneficial facilitate transformations in various areas chemistry. Today, a systematic body evidence indicates that mechanochemistry holds great promise become game‐changer synthesis. Not only does permit access products are inaccessible by established means (e.g. purely thermal activation), mechanochemical reactions often outperform their solution‐based counterparts terms sustainability. Most carried out ball milling techniques involve solids and liquids, but number with gaseous reactants is increasing. The aim this Minireview provide an overview involving samples highlight advances technology for safe handling reagents. Examples proceeding at interface solid–/liquid–/gas–gas led significant improvements reactivity or selectivity will also be highlighted.

Language: Английский

Citations

329

Solvent effects in palladium catalysed cross-coupling reactions DOI
James Sherwood, James H. Clark, Ian J. S. Fairlamb

et al.

Green Chemistry, Journal Year: 2019, Volume and Issue: 21(9), P. 2164 - 2213

Published: Jan. 1, 2019

A review of the solvent effects that control productivity cross-coupling reactions, and suggested safer alternative solvents.

Language: Английский

Citations

253

Mechanochemical synthesis of highly porous materials DOI
Barbara Szczęśniak, Sylwia Głowniak, J. Choma

et al.

Materials Horizons, Journal Year: 2020, Volume and Issue: 7(6), P. 1457 - 1473

Published: Jan. 1, 2020

Mechanochemistry became a powerful and popular method for the preparation of various porous materials.

Language: Английский

Citations

247

Mechanochemistry for Synthesis DOI
Tomislav Friščić, Cristina Mottillo, Hatem M. Titi

et al.

Angewandte Chemie, Journal Year: 2019, Volume and Issue: 132(3), P. 1030 - 1041

Published: July 11, 2019

Abstract Mechanochemical solvent‐free reactions by milling, grinding or other types of mechanical action have emerged as a viable alternative to solution chemistry. Mechanochemistry offers not only possibility eliminate the need for bulk solvent use, and reduce generation waste, but it also unlocks door different reaction environment in which synthetic strategies, molecules previously accessible solution, can be achieved. This Minireview examines potential mechanochemistry chemical materials synthesis, providing cross‐section recent developments using ball milling formation based on covalent coordination bonds.

Language: Английский

Citations

238

The mechanochemical synthesis of polymers DOI Creative Commons
Annika Krusenbaum, Sven Grätz, Getinet Tamiru Tigineh

et al.

Chemical Society Reviews, Journal Year: 2022, Volume and Issue: 51(7), P. 2873 - 2905

Published: Jan. 1, 2022

Mechanochemistry enables solvent-free syntheses of even novel polymer structures without the need monomer solubility.

Language: Английский

Citations

201

Mechanochemical Cross-Coupling Reactions DOI Creative Commons
Koji Kubota, Hajime Ito

Trends in Chemistry, Journal Year: 2020, Volume and Issue: 2(12), P. 1066 - 1081

Published: Oct. 20, 2020

Language: Английский

Citations

191